Nanocomposites of graphene oxide, Ag nanoparticles, and magnetic ferrite nanoparticles for elemental mercury (Hg0) removal

Yuxi Liu; Chong Tian; Bin Yan; Qingye Lu; Yijun Xie; Jian Chen; Rajender Gupta; Zhenghe Xu; Steven M. Kuznicki; Qingxia Liu; Hongbo Zeng

doi:10.1039/C4RA16016A

Nanocomposites of graphene oxide, Ag nanoparticles, and magnetic ferrite nanoparticles for elemental mercury (Hg⁰) removal†

Yuxi Liu,^a Chong Tian,^ab Bin Yan,^a Qingye Lu,^a Yijun Xie,^a Jian Chen,^c Rajender Gupta,^a Zhenghe Xu,^a Steven M. Kuznicki,^a Qingxia Liu^a and Hongbo Zeng*^a

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* Corresponding authors

^a Department of Chemical and Material Engineering, University of Alberta, Edmonton, AB, Canada
E-mail: Hongbo.Zeng@ualberta.ca
Fax: +1-780-492-2881
Tel: +1-780-492-1044

^b State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, P. R. China

^c National Institute for Nanotechnology, National Research Council, Edmonton, Alberta, Canada

Abstract

Mercury emission from combustion flue gas causes considerable environmental challenges and serious adverse health threats, and elemental mercury (Hg⁰) is the most challenging chemical form for removal. In this work, four types of graphene oxide (GO) based composite adsorbents were successfully synthesized by depositing Ag nanoparticles (NPs) and/or magnetic ferrite NPs on GO sheets (denoted as GO, GO–Ag, MGO and MGO–Ag), characterized and applied for the removal of Hg⁰ for the first time. The presence of Ag NPs on GO greatly enhances the Hg⁰ removal capability of GO–Ag and MGO–Ag as compared to that of pure GO, which is mainly attributed to the amalgamation of Hg⁰ on Ag NPs. MGO–Ag shows the best Hg⁰ removal performance and thermal tolerance among the four types of adsorbents developed, which can effectively capture Hg⁰ up to 150–200 °C in a simulated flue gas environment and can be also effectively recycled and reused. Our results indicate that the graphene oxide based composites (i.e. MGO–Ag) have significant potential applications for mercury emission control in coal-fired power plants.

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Nanocomposites of graphene oxide, Ag nanoparticles, and magnetic ferrite nanoparticles for elemental mercury (Hg⁰) removal†

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Nanocomposites of graphene oxide, Ag nanoparticles, and magnetic ferrite nanoparticles for elemental mercury (Hg⁰) removal

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