β-Cyclodextrin catalysed C–C bond formation via C(sp3)–H functionalization of 2-methyl azaarenes with diones in aqueous medium

Atul Kumar; Ratnakar Dutt Shukla

doi:10.1039/C4GC02287D

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β-Cyclodextrin catalysed C–C bond formation via C(sp³)–H functionalization of 2-methyl azaarenes with diones in aqueous medium†

Atul Kumar*^ab and Ratnakar Dutt Shukla^a

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* Corresponding authors

^a Medicinal and Process Chemistry Division, CSIR-Central Drug Research Institute (CDRI), Lucknow, India

^b Academy of Scientific & Innovative Research (AcSIR), New Delhi, India
E-mail: dratulsax@gmail.com
Fax: +91-522-26234051
Tel: +91-522-2612411

Abstract

The first β-cyclodextrin catalysed C(sp³)–H functionalization of 2-alkyl-azaarenes with homocyclic as well as heterocyclic diones in water has been developed. This biomimetic catalyst oriented methodology provides a sustainable and green protocol for C–H functionalization, an area mainly dominated by transition metals.

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Article information

DOI: https://doi.org/10.1039/C4GC02287D
Article type: Communication
Submitted: 20 Nov 2014
Accepted: 04 Dec 2014
First published: 05 Dec 2014

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Green Chem., 2015,17, 848-851

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β-Cyclodextrin catalysed C–C bond formation via C(sp³)–H functionalization of 2-methyl azaarenes with diones in aqueous medium

A. Kumar and R. Dutt Shukla, Green Chem., 2015, 17, 848 DOI: 10.1039/C4GC02287D

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