Issue 94, 2014
From the journal:

Chemical Communications

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides†

Dengke Li,a   Ning Xu,a   Yicheng Zhanga  and  Lei Wang*ab  

* Corresponding authors

a Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. China
E-mail: leiwang@chnu.edu.cn
Fax: +86-561-309-0518
Tel: +86-561-380-2069

b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. China

Abstract

An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl acylperoxides to afford the corresponding ortho-arylation products, and N-methoxyarylamides generated phenanthridinones.

Graphical abstract: A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

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Article information

DOI
https://doi.org/10.1039/C4CC06457G
Article type
Communication
Submitted
16 Aug 2014
Accepted
03 Sep 2014
First published
06 Oct 2014

Chem. Commun., 2014,50, 14862-14865

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A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

D. Li, N. Xu, Y. Zhang and L. Wang, Chem. Commun., 2014, 50, 14862 DOI: 10.1039/C4CC06457G

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