Issue 89, 2014
From the journal:

Chemical Communications

Procedure-dependent construction of two isomers of trimeric self-assembled boronic esters†

Kosuke Ono,a   Ryo Aizawa,a   Taiki Yamano,a   Suguru Ito,a   Nobuhiro Yasuda,b   Kohei Johmoto,c   Hidehiro Uekusac  and  Nobuharu Iwasawa*a  

* Corresponding authors

a Department of Chemistry, Tokyo Institute of Technology and CREST, Japan Science and Technology Agency (JST), 2-12-1, O-okayama, Meguro-ku, Tokyo 152-8551, Japan
E-mail: niwasawa@chem.titech.ac.jp

b Japan Synchrotron Radiation Research Institute/Spring-8, 1-1-1 Kouto, Sayo-gun, Hyogo 679-5198, Japan

c Department of Chemistry and Materials Science, Tokyo Institute of Technology and CREST, Japan Science and Technology Agency (JST), 2-12-1, O-okayama, Meguro-ku, Tokyo 152-8551, Japan

Abstract

A procedure-dependent selective construction of two isomers of trimeric boronic esters was realized. A capsule-like trimeric boronic ester was constructed by the direct connection of two kinds of self-assembled boronic esters via [3+2] cycloaddition, while the tricyclic trimeric boronic ester was obtained by the self-assembly of pre-connected components.

Graphical abstract: Procedure-dependent construction of two isomers of trimeric self-assembled boronic esters

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Article information

DOI
https://doi.org/10.1039/C4CC05836D
Article type
Communication
Submitted
28 Jul 2014
Accepted
09 Sep 2014
First published
10 Sep 2014

Chem. Commun., 2014,50, 13683-13686

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Procedure-dependent construction of two isomers of trimeric self-assembled boronic esters

K. Ono, R. Aizawa, T. Yamano, S. Ito, N. Yasuda, K. Johmoto, H. Uekusa and N. Iwasawa, Chem. Commun., 2014, 50, 13683 DOI: 10.1039/C4CC05836D

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