Issue 11, 1995

Single crystal structure of [(Me2N-C6H4)2C++C(C6H4-NMe2)2](I3)2: a twisted tetraphenylethylene dication with a C–C single bond

Abstract

The cyanine distortion of doubly charged ethylenes leading to twisted molecular halves connected by a C–C single bond inciudes tetrakis(p-dimethylaminophenyl)ethylene, which on twofold oxidation with iodine increases its twist angle ω from 19 to 53° and its central C[double bond, length half m-dash]C bond length from 135 to 150 pm as predicted by PM3 calculations.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 1111-1112

Single crystal structure of [(Me2N-C6H4)2C++C(C6H4-NMe2)2](I3)2: a twisted tetraphenylethylene dication with a C–C single bond

H. Bock, C. Näther and Z. Havlas, J. Chem. Soc., Chem. Commun., 1995, 1111 DOI: 10.1039/C39950001111

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