Issue 3, 1990

Transformation of O2S(C[triple bond, length half m-dash]CCMe3)2 to an exoalkylidene thiete 1,1-dioxide ligand by Pt-H addition and rearrangement reactions

Abstract

Addition of a Pt-H bond to the C[triple bond, length half m-dash]C bond of an alkynyl substituent of a dialkynylsuiphone occurs regioselectively to give an exoalkylidene thiete 1, 1-dioxide ligand following a subsequent insertion and rearrangement of the second alkynyl substituent; a proposed mechanism for the unusual formation of the heterocyclic ligand is presented.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1990, 215-217

Transformation of O2S(C[triple bond, length half m-dash]CCMe3)2 to an exoalkylidene thiete 1,1-dioxide ligand by Pt-H addition and rearrangement reactions

C. M. Lukehart, A. T. McPhail, D. R. Mcphail and M. D. Owen, J. Chem. Soc., Chem. Commun., 1990, 215 DOI: 10.1039/C39900000215

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements