2H-thiopyrans as intermediates in the rearrangement of thiophenium bisalkoycarbonylmethylides to thiophene-2-malonates; the crystal and molecular structure of 2,2-bis-t-butoxycarbonyl-5-bromo-2H-thiopyran and 2,2-bis-t-butoxycarbonyl-6-bromo-2H-thiopyran

Timothy Bowles; Ray Jones; Alexander E. A. Porter; Josef A. Rechka; Henry S. Rzepa; David J. Williams

doi:10.1039/C39850001590

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2H-thiopyrans as intermediates in the rearrangement of thiophenium bisalkoycarbonylmethylides to thiophene-2-malonates; the crystal and molecular structure of 2,2-bis-t-butoxycarbonyl-5-bromo-2H-thiopyran and 2,2-bis-t-butoxycarbonyl-6-bromo-2H-thiopyran

Timothy Bowles, Ray Jones, Alexander E. A. Porter, Josef A. Rechka, Henry S. Rzepa and David J. Williams

Abstract

2H-Thiopyrans have been observed as intermediates in the rearrangement of thiophenium bisalkoxy-carbonylmethylides to thiophene-2-malonates.

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DOI: https://doi.org/10.1039/C39850001590
Article type: Paper

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J. Chem. Soc., Chem. Commun., 1985, 1590-1592

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2H-thiopyrans as intermediates in the rearrangement of thiophenium bisalkoycarbonylmethylides to thiophene-2-malonates; the crystal and molecular structure of 2,2-bis-t-butoxycarbonyl-5-bromo-2H-thiopyran and 2,2-bis-t-butoxycarbonyl-6-bromo-2H-thiopyran

T. Bowles, R. Jones, A. E. A. Porter, J. A. Rechka, H. S. Rzepa and D. J. Williams, J. Chem. Soc., Chem. Commun., 1985, 1590 DOI: 10.1039/C39850001590

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Journal of the Chemical Society, Chemical Communications

2H-thiopyrans as intermediates in the rearrangement of thiophenium bisalkoycarbonylmethylides to thiophene-2-malonates; the crystal and molecular structure of 2,2-bis-t-butoxycarbonyl-5-bromo-2H-thiopyran and 2,2-bis-t-butoxycarbonyl-6-bromo-2H-thiopyran

Abstract

Article information

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2H-thiopyrans as intermediates in the rearrangement of thiophenium bisalkoycarbonylmethylides to thiophene-2-malonates; the crystal and molecular structure of 2,2-bis-t-butoxycarbonyl-5-bromo-2H-thiopyran and 2,2-bis-t-butoxycarbonyl-6-bromo-2H-thiopyran

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