SCHEDULED MAINTENANCE
The 1,4 concerted addition of Me3SnH to the singlet excited penta-1,3-dienes yields cis- and trans- adducts according to a stereochemistry which is incompatible with an allylmethylene relaxed configuration and suggests a doubly state.
M. Bigwood and S. Boué, J. Chem. Soc., Chem. Commun., 1974, 529 DOI: 10.1039/C39740000529
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