Issue 9, 2010
From the journal:

Dalton Transactions

Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

Anthony C. Coleman,a   Nicola M. Boyle,a   Conor Long,a   Ramunas Augulis,b   Audrius Pugzlys,†b   Paul H. M. van Loosdrecht,b   Wesley R. Browne,c   Ben L. Feringa,c   Kate L. Ronayned  and  Mary T. Pryce*a  

* Corresponding authors

a School of Chemical Sciences, Dublin City University, Dublin 9, Ireland
E-mail: mary.pryce@dcu.ie
Fax: 00353-1-7005503
Tel: 00353-1-700-8005

b Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

c Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, Groningen, The Netherlands

d Lasers for Science Facility, The Rutherford Appelton Laboratories, Didcot, Oxfordshire, UK

Abstract

The femto- and picosecond time resolved spectroscopy of (η6-cis-stilbene)Cr(CO)3 provides evidence for three optically accessible excited states one leading to cis-trans isomerisation of the coordinated stilbene ligand and another which results in a slow release of CO.

Graphical abstract: Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

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Article information

DOI
https://doi.org/10.1039/B925349C
Article type
Communication
Submitted
04 Nov 2009
Accepted
15 Dec 2009
First published
12 Jan 2010

Dalton Trans., 2010,39, 2201-2203

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Optically induced cis-trans isomerisation of (η6-cis-stilbene)Cr(CO)3

A. C. Coleman, N. M. Boyle, C. Long, R. Augulis, A. Pugzlys, P. H. M. van Loosdrecht, W. R. Browne, B. L. Feringa, K. L. Ronayne and M. T. Pryce, Dalton Trans., 2010, 39, 2201 DOI: 10.1039/B925349C

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