Issue 1, 2003
From the journal:

Journal of Materials Chemistry

Intercalation of tetraazamacrocycles into molybdenum disulfide†

Rabin Bissessur,*a   Robert I. Haines*a  and  Ralf Brüningb  

* Corresponding authors

a Department of Chemistry, University of Prince Edward Island, Charlottetown, Prince Edward Island, Canada
E-mail: rabissessur@upei.ca, rhaines@upei.ca

b Department of Physics, Mount Allison University, Sackville, New Brunswick, Canada

Abstract

A series of intercalation compounds of tetraazamacrocycles in molybdenum disulfide have been synthesized using the exfoliation and restacking properties of LiMoS2. The sandwiched compounds were characterized by powder X-ray diffraction, thermogravimetric analyses, differential scanning calorimetry, and four-probe electrical conductivity measurements. The interlayer spacing of the intercalation compound was found to be dependent on the size of the macrocyclic ligand, indicating that the intercalated macrocycles are co-planar with the MoS2 sheets.

Graphical abstract: Intercalation of tetraazamacrocycles into molybdenum disulfide

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Article information

DOI
https://doi.org/10.1039/B208237N
Article type
Paper
Submitted
22 Aug 2002
Accepted
01 Nov 2002
First published
21 Nov 2002

J. Mater. Chem., 2003,13, 44-49

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Intercalation of tetraazamacrocycles into molybdenum disulfide

R. Bissessur, R. I. Haines and R. Brüning, J. Mater. Chem., 2003, 13, 44 DOI: 10.1039/B208237N

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