Issue 13, 2000
From the journal:

Chemical Communications

Polymerisation of acrylonitrile with di(organoimido)chromium(vi) complexes

Ulrich Siemeling,†*a   Lars Kölling,a   Anja Stammler,a   Hans-Georg Stammler,a   Eric Kaminskib  and  Gerhard Finkb  

* Corresponding authors

a Fakultät für Chemie, Universität Bielefeld, Universitätsstraße 25, Bielefeld, Germany

b Max-Planck-Institut für Kohlenforschung, Kaiser-Wilhelm-Platz 1, Mülheim an der Ruhr, Germany

Abstract

[(ButN)2Cr(CH2Ph)2 ] 1 and [(NCMe2CH2CH2CMe2N)Cr- (CH2Ph)2] 2 are robust single-component catalysts for the polymerisation of acrylonitrile, which afford high-molecular-weight PAN and also allow acrylonitrile–methyl methacrylate copolymerisation; owing to its strained seven-membered chelate ring, 2 exhibits exceptionally small imido bond angles.

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B002310H
Article type
Communication
Submitted
20 Mar 2000
Accepted
25 May 2000
First published
14 Jun 2000

Chem. Commun., 2000, 1177-1178

Permissions

Request permissions

Polymerisation of acrylonitrile with di(organoimido)chromium(VI) complexes

U. Siemeling, L. Kölling, A. Stammler, H. Stammler, E. Kaminski and G. Fink, Chem. Commun., 2000, 1177 DOI: 10.1039/B002310H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements