Issue 5, 1990

Asymmetric synthesis of β-phenylserines by condensation of benzaldehyde with zinc(II) and copper(II) complexes of (1R)-3-hydroxymethylenebornan-2-one glycine imines

Abstract

The condensation between benzaldehyde and the zinc(II) and copper(II) complexes of the glycine imines of (1R)-3-hydroxymethylenebornan-2-one in the presence of strong bases has been studied. The diastereo- and enantio-selectivity of the reaction together with the spectroscopic characterization of the metal complexes and the corresponding enolate intermediates are reported.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1990, 771-775

Asymmetric synthesis of β-phenylserines by condensation of benzaldehyde with zinc(II) and copper(II) complexes of (1R)-3-hydroxymethylenebornan-2-one glycine imines

L. Casella, M. Gullotti, G. Jommi, R. Pagliarin and M. Sisti, J. Chem. Soc., Perkin Trans. 2, 1990, 771 DOI: 10.1039/P29900000771

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