SCHEDULED MAINTENANCE
The secondary alcohols 3, 4 and 10 have been converted into the corresponding lactones using Acinetobacter calcoaceticus NCIMB 9871: the transformations (endo-4)⇒6+11 and 10⇒8+9 can be conducted in vitro using a coupled enzyme system (Thermoanaerobium brockii dehydrogenase and Acinetobacter calcoaceticus monooxygenase) with in situ recycling of NADPH/NADP+.
A. J. Willetts, C. J. Knowles, M. S. Levitt, S. M. Roberts, H. Sandey and N. F. Shipston, J. Chem. Soc., Perkin Trans. 1, 1991, 1608 DOI: 10.1039/P19910001608
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