Issue 5, 1993
From the journal:

Journal of the Chemical Society, Dalton Transactions

Reactivity of the [Re[triple bond, length half m-dash]NR]3+ and [Re[triple bond, length half m-dash]N]2+ cores toward bis(diphenylphosphino)amine and its derivatives. Synthesis and crystal structures

Roberto Rossi,   Andrea Marchi,   Lorenza Marvelli,   Luciano Magon,   Maurizio Peruzzini,   Umberto Casellato  and  Rodolfo Graziani  

Abstract

The complexes fac-[Re(NMe)Cl3{NH(PPh2)2-P,P′}]1, [ReNCl{NH(PPh2)2-P,P′}2]X (X = Cl 2 or BPh42a), [Re(NMe) Cl2{N(XPPh2)2-X,X′}(PPh3)](X = 0 3, S 4 or Se 8), [Re(NMe)Cl{N(XPPh2)2-X,X′}2](X = S 5 or Se 9), [ReNCl{N(SPPh2)2-S,S′}(PPh3)]6, [ReN{N(XPPh2)2-X,X′)2](X = S 7 or Se 10) and trans-[ReOCl2{N(OPPh2)2-O,O′}(AsPh3)]11 were obtained by treatment of [Re(NMe)Cl3(PPh3)2], [ReNCl2(PPh3)2] or [ReOCl3(AsPh3)2] with the appropriate ligand under different experimental conditions. The structures of complexes 1, 2a and 6 were determined by X-ray crystallography. In 1 and 2a the Re atom is six-co-ordinate in a distorted octahedral configuration, whereas in 6 the Re atom is five-co-ordinate square pyramidal with the N atom in the apical position.

About
Cited by
Related
Download options Please wait...

Article information

DOI
https://doi.org/10.1039/DT9930000723
Article type
Paper

J. Chem. Soc., Dalton Trans., 1993, 723-729

Permissions

Request permissions

Reactivity of the [Re[triple bond, length half m-dash]NR]3+ and [Re[triple bond, length half m-dash]N]2+ cores toward bis(diphenylphosphino)amine and its derivatives. Synthesis and crystal structures

R. Rossi, A. Marchi, L. Marvelli, L. Magon, M. Peruzzini, U. Casellato and R. Graziani, J. Chem. Soc., Dalton Trans., 1993, 723 DOI: 10.1039/DT9930000723

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements