Issue 77, 2013
From the journal:

Chemical Communications

The influence of π-conjugated moieties on the thermodynamics of cooperatively self-assembling tricarboxamides†

Fátima García,a   Peter A. Korevaar,b   Arno Verlee,b   E. W. Meijer,b   Anja R. A. Palmans*b  and  Luis Sánchez*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain
E-mail: lusamar@quim.ucm.es
Fax: +34 913944103

b Laboratory of Macromolecular and Organic Chemistry and Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands
E-mail: a.palmans@tue.nl

Abstract

A detailed investigation of the self-assembly behaviour of C3-symmetrical tricarboxamides reveals that a larger π-conjugated core does not increase the stability of assemblies in an apolar solvent but makes the system more sensitive to destabilization by addition of a good solvent.

Graphical abstract: The influence of π-conjugated moieties on the thermodynamics of cooperatively self-assembling tricarboxamides

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Article information

DOI
https://doi.org/10.1039/C3CC43845G
Article type
Communication
Submitted
22 May 2013
Accepted
25 Jul 2013
First published
29 Jul 2013

Chem. Commun., 2013,49, 8674-8676

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The influence of π-conjugated moieties on the thermodynamics of cooperatively self-assembling tricarboxamides

F. García, P. A. Korevaar, A. Verlee, E. W. Meijer, A. R. A. Palmans and L. Sánchez, Chem. Commun., 2013, 49, 8674 DOI: 10.1039/C3CC43845G

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