Pentamethylcyclopentadienyliridium(III) complexes, e.g.[(C5Me4CH3)Ir(Me)(Ph)(CO)] are metallated by BusLi at a ring methyl; the resultant lithio-complex reacts with organic halides, ketones and CO2 to give the appropriately substituted [(C5Me4CH2W)IrX(Me)(CO)](X = Ph; W = SiMe3, CH2![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CHCH2, PhCH2, Ph2COH, PhMeCOH, or X = Cl; W = CO2H, CO2Me).
J. A. Miguel-Garcia and P. M. Maitlis, J. Chem. Soc., Chem. Commun., 1990, 1472 DOI: 10.1039/C39900001472
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