Issue 5, 2008
From the journal:

CrystEngComm

Structures of metal-organic networks based on flexible 1,1′-(1,4-butanediyl)bis(imidazole-2-phenyl) ligand†‡

Ying-Ying Liu,a   Jian-Fang Ma,*a   Jin Yang,a   Ji-Cheng Maa  and  Guang-Ju Pinga  

* Corresponding authors

a Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun, People's Republic of China
E-mail: jianfangma@yahoo.com.cn

Abstract

A new neutral ligand 1,1′-(1,4-butanediyl)bis(imidazole-2-phenyl) (bbip) and six coordination polymers, namely [Zn(o-bdc)(bbip)]·H2O (1), [Zn(m-bdc)(bbip)]·H2O (2), [Cd(m-bdc)(bbip)] (3), [Zn(OH–bdc)(bbip)] (4), [Cd(OH–bdc)(bbip)] (5) and [Zn(fum)(bbip)]·H2O (6) (where o-H2bdc = 1,2-benzenedicarboxylic acid, m-H2bdc = 1,3-benzenedicarboxylic acid, OH–H2bdc = 5-hyroxyisophthalic acid and H2fum = fumaric acid), are described. Compound 1 shows a one-dimensional double-stranded chain structure. Compounds 2 and 4 possess 2D polymeric layers, and the layers are connected through van der Waals forces and hydrogen bonds into 3D supramolecular structures, respectively. Compounds 3, 5 and 6 exhibit 3-fold interpenetrating diamondoid networks. The luminescent properties for these compounds in the solid state are discussed.

Graphical abstract: Structures of metal-organic networks based on flexible 1,1′-(1,4-butanediyl)bis(imidazole-2-phenyl) ligand

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/B714399K
Article type
Paper
Submitted
18 Sep 2007
Accepted
19 Dec 2007
First published
22 Jan 2008

CrystEngComm, 2008,10, 565-572

Permissions

Request permissions

Structures of metal-organic networks based on flexible 1,1′-(1,4-butanediyl)bis(imidazole-2-phenyl) ligand

Y. Liu, J. Ma, J. Yang, J. Ma and G. Ping, CrystEngComm, 2008, 10, 565 DOI: 10.1039/B714399K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements