Solvent-dependent 44 square grid and 64.82 NbO frameworks formed by Cu(Pyac)2(bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II))

Banglin Chen; Frank R. Fronczek; Andrew W. Maverick

doi:10.1039/B305457H

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Solvent-dependent 4⁴ square grid and 6⁴.8² NbO frameworks formed by Cu(Pyac)₂ (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(ii))†

Banglin Chen,^a Frank R. Fronczek^a and Andrew W. Maverick*^a

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^a Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA

Abstract

The title compound crystallizes from anhydrous solvents in a simple square-grid topology, but when water is present, crystals form with an unusual interpenetrated 3D NbO topology whose pores contain hydrogen-bonded solvent molecules.

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Article information

DOI: https://doi.org/10.1039/B305457H
Article type: Communication
Submitted: 14 May 2003
Accepted: 24 Jun 2003
First published: 28 Jul 2003

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Chem. Commun., 2003, 2166-2167

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Solvent-dependent 4⁴ square grid and 6⁴.8² NbO frameworks formed by Cu(Pyac)₂ (bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II))

B. Chen, F. R. Fronczek and A. W. Maverick, Chem. Commun., 2003, 2166 DOI: 10.1039/B305457H

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