Issue 2, 2003
From the journal:

New Journal of Chemistry

A novel copper(i) complex that is a monomeric single helix in solid state but a dimeric double helix in solution

Shubhamoy Chowdhury,a   Peter B. Iveson,b   Michael G. B. Drew,b   Derek A. Tocherc  and  Dipankar Datta*a  

* Corresponding authors

a Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, Calcutta, India
E-mail: icdd@mahendra.iacs.res.in

b Department of Chemistry, University of Reading, Whiteknights, Reading, UK

c Department of Chemistry, University College London, 20 Gordon Street, London, UK

Abstract

Single helical [CuIL]ClO4·½CH2Cl2 (L = 1∶2 condensate of benzil dihydrazone and 2-acetylpyridine) unfolds and coils up in CH2Cl2 solution to generate double helical [CuI2L2]2+.

Graphical abstract: A novel copper(i) complex that is a monomeric single helix in solid state but a dimeric double helix in solution

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Article information

DOI
https://doi.org/10.1039/B207057J
Article type
Letter
Submitted
15 Jul 2002
Accepted
30 Sep 2002
First published
20 Nov 2002

New J. Chem., 2003,27, 193-196

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A novel copper(I) complex that is a monomeric single helix in solid state but a dimeric double helix in solution

S. Chowdhury, P. B. Iveson, M. G. B. Drew, D. A. Tocher and D. Datta, New J. Chem., 2003, 27, 193 DOI: 10.1039/B207057J

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