Issue 5, 2001
From the journal:

Journal of the Chemical Society, Dalton Transactions

Syntheses and structures of six chain-, ladder- and grid-like co-ordination polymers constructed from μ-hexamethylenetetramine and silver salts

Shao-Liang Zheng,a   Ming-Liang Tong,*a   Xiao-Lan Yua  and  Xiao-Ming Chen*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, Zhongshan University, Guangzhou, PR China
E-mail: cescxm@zsu.edn.cn

Abstract

Six interesting co-ordination polymers [Ag(μ-hmt)(hba)(H2O)] 1, [Ag(μ-hmt)(aba)(H2O)] 2, [Ag2(μ-hmt)2(bca)(H2O)2]·H2O 3, [Ag(μ-hmt)(ina)]·0.5H2O 4, [Ag(μ-hmt)(bsa)] 5, [Ag2(μ-hmt)2(bda)]·4H2O 6 (hmt = hexamethylenetetramine, hba = 4-hydroxybenzoate, aba = 4-aminobenzoate, bca = 4,4′-biphenyldicarboxylate, ina = isonicotinate, bsa = benzenesulfinate, bda = 1,4-butanedioate), have been prepared and structurally characterised. These co-ordination frameworks, all based on the Ag(μ-hmt) chains, exhibit new structural varieties in the Ag–hmt system, such as the chains in 1 and 2, ladders in 3, grids in 4, double-chains in 5, as well as rectangular grids with double-chains in 6. The result shows that the structural variations are mainly dependent upon the nature of the anionic ligands used.

Graphical abstract: Syntheses and structures of six chain-, ladder- and grid-like co-ordination polymers constructed from μ-hexamethylenetetramine and silver salts

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Article information

DOI
https://doi.org/10.1039/B009068I
Article type
Paper
Submitted
13 Nov 2000
Accepted
19 Dec 2000
First published
09 Feb 2001

J. Chem. Soc., Dalton Trans., 2001, 586-592

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Syntheses and structures of six chain-, ladder- and grid-like co-ordination polymers constructed from μ-hexamethylenetetramine and silver salts

S. Zheng, M. Tong, X. Yu and X. Chen, J. Chem. Soc., Dalton Trans., 2001, 586 DOI: 10.1039/B009068I

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