Issue 10, 1975
From the journal:

Journal of the Chemical Society, Dalton Transactions

Crystal and molecular structures of aquahalogenovanadium(III) complexes. Part I. X-Ray crystal structure of trans-tetrakisaquadibromo-vanadium(III) bromide dihydrate and the isomorphous chloro-compound

William F. Donovan  and  Peter W. Smith  

Abstract

Crystals of (I), trans-[VBr2(H2O)4]Br,2H2O, are monoclinic, space group P21/c, with a= 6·408(4), b= 6·550(4), c= 12·300(7)Å, β= 96·15(5)°, and Z= 2. The structure was determined by Patterson and Fourier methods from 372 visually estimated reflections, and refined by full-matrix least-squares to R 0·11. V–Br Is 2·539(1) and V–OH2 1·967(4) and 1·977(5)Å.

For (II), the isomorphous chloro-compound, a= 6·430(4), b= 6·439(4), c= 11·901(6)Å, β= 98·8(1)°, Z= 2; 126 visually estimated reflections were refined to R 0·12. Bond lengths are: V–Cl 2·361(2), V–OH2 2·024(5) and 1·961 (7)Å.

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Article information

DOI
https://doi.org/10.1039/DT9750000894
Article type
Paper

J. Chem. Soc., Dalton Trans., 1975, 894-896

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Crystal and molecular structures of aquahalogenovanadium(III) complexes. Part I. X-Ray crystal structure of trans-tetrakisaquadibromo-vanadium(III) bromide dihydrate and the isomorphous chloro-compound

W. F. Donovan and P. W. Smith, J. Chem. Soc., Dalton Trans., 1975, 894 DOI: 10.1039/DT9750000894

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