Abstract
Viscous flow is familiar and useful, yet the underlying physics is surprisingly subtle and complex. Recent experiments and simulations show that the textbook assumption of 'no slip at the boundary' can fail greatly when walls are sufficiently smooth. The reasons for this seem to involve materials chemistry interactions that can be controlled — especially wettability and the presence of trace impurities, even of dissolved gases. To discover what boundary condition is appropriate for solving continuum equations requires investigation of microscopic particulars. Here, we draw attention to unresolved topics of investigation and to the potential to capitalize on 'slip at the wall' for purposes of materials engineering.
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Photo courtesy of Aurélie Lafuma and David Quéré, Collège de France, Paris.


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Acknowledgements
For discussions, we are indebted to John Brady, Michel Cloître, Jack Douglas, Steve Meeker, Hugh Spikes, Jan Vermant and Norman Wagner. This work was supported in part by a grant to H.L. by the postdoctoral fellowship program from Korea Science & Engineering Foundation (KOSEF). This work was supported by the U.S. Department of Energy, Division of Materials Science, under Award No. DEFG02-91ER45439 through the Frederick Seitz Materials Research Laboratory at the University of Illinois at Urbana-Champaign.
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Granick, S., Zhu, Y. & Lee, H. Slippery questions about complex fluids flowing past solids. Nature Mater 2, 221–227 (2003). https://doi.org/10.1038/nmat854
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DOI: https://doi.org/10.1038/nmat854