Letters to Nature

Nature 410, 192-194 (8 March 2001) | doi:10.1038/35065571; Received 23 October 2000; Accepted 29 January 2001

An efficient room-temperature silicon-based light-emitting diode

Wai Lek Ng1, M. A. Lourenço1, R. M. Gwilliam1, S. Ledain2, G. Shao2 and K. P. Homewood1

  1. School of Electronic Engineering, Information Technology & Mathematics;
  2. School of Mechanical and Materials Engineering, University of Surrey, Guildford, Surrey, GU2 7XH, UK

Correspondence to: K. P. Homewood1 Correspondence and requests for materials should be addressed to K.P.H. (e-mail: Email: k.homewood@eim.surrey.ac.uk).

There is an urgent requirement for an optical emitter that is compatible with standard, silicon-based ultra-large-scale integration (ULSI) technology1. Bulk silicon has an indirect energy bandgap and is therefore highly inefficient as a light source, necessitating the use of other materials for the optical emitters. However, the introduction of these materials is usually incompatible with the strict processing requirements of existing ULSI technologies. Moreover, as the length scale of the devices decreases, electrons will spend increasingly more of their time in the connections between components; this interconnectivity problem could restrict further increases in computer chip processing power and speed in as little as five years. Many efforts have therefore been directed, with varying degrees of success, to engineering silicon-based materials that are efficient light emitters2, 3, 4, 5, 6, 7. Here, we describe the fabrication, using standard silicon processing techniques, of a silicon light-emitting diode (LED) that operates efficiently at room temperature. Boron is implanted into silicon both as a dopant to form a p–n junction, as well as a means of introducing dislocation loops. The dislocation loops introduce a local strain field, which modifies the band structure and provides spatial confinement of the charge carriers. It is this spatial confinement which allows room-temperature electroluminescence at the band-edge. This device strategy is highly compatible with ULSI technology, as boron ion implantation is already used as a standard method for the fabrication of silicon devices.

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