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Crystal Structure of β-D-Cellotetraose and its Relationship to Cellulose

Abstract

CELLULOSE is a straight chain polymer of 1→4 linked β-D-glucopyranose residues, the most important polymorphs of which are natural cellulose (cellulose I) and regenerated or mercerized cellulose (cellulose II). Although these forms have been extensively studied as fibres and orientated films, so far no fully satisfactory structural description has been advanced for either1,2 or in fact for any of the other cellulose allotropes.

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References

  1. Ellis, K. C., and Warwicker, J. O., J. Polymer Sci., 56, 339 (1962).

    Article  ADS  CAS  Google Scholar 

  2. Jones, D. W., J. Polymer Sci., 42, 173 (1960).

    Article  ADS  CAS  Google Scholar 

  3. Howsmon, J. A., and Tisson, W. A., in Cellulose and Cellulose Derivatives (second ed.) (edit. by Ott, E., Spurlin, H. M., and Grafflin, M. W.), 4 (Interscience Publishers, 1955).

    Google Scholar 

  4. Marrinan, H. J., and Mann, J. J., J. Appl. Chem., 4, 204 (1954).

    Article  CAS  Google Scholar 

  5. Wellard, H. J., J. Polymer Sci., 13, 471 (1954).

    Article  ADS  CAS  Google Scholar 

  6. Fridrichsons, J., Mathieson, A. McL., and Stiff, G. M., Rev. Sci. Instrum., 30, 375 (1959).

    Article  ADS  Google Scholar 

  7. Brown, C. J., J. Chem. Soc., A, 927 (1966).

  8. Jacobson, R. A., Wunderlich, J. A., and Lipscomb, W. N., Acta Cryst., 14, 598 (1961).

    Article  CAS  Google Scholar 

  9. Ferrier, W. G., Acta Cryst., 16, 1023 (1963).

    Article  CAS  Google Scholar 

  10. Brown, C. J., Cox, E. G., and Llewellyn, F. J., J. Chem. Soc., A, 922 (1966).

  11. Mathieson, A. McL., and Poppleton, B. J., Acta Cryst., 21, 72 (1966).

    Article  CAS  Google Scholar 

  12. Cox, E. G., Goodwin, T. H., Wagstaff, A. I., J. Chem. Soc., 978 (1935).

  13. Andress, R. K., Z. Phys. Chem., B,2, 380 (1929).

    CAS  Google Scholar 

  14. Meyer, K. H., and Mark, H., Z. Phys. Chem., B,2, 115 (1929).

    Google Scholar 

Download references

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POPPLETON, B., MATHIESON, A. Crystal Structure of β-D-Cellotetraose and its Relationship to Cellulose. Nature 219, 1046–1048 (1968). https://doi.org/10.1038/2191046a0

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