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PALEOCEANOGRAPHY, VOL. 21, PA4209, doi:10.1029/2005PA001239, 2006

Sediment Cd and Mo accumulation in the oxygen-minimum zone off western Baja California linked to global climate over the past 52 kyr

Walter E. Dean

U.S. Geological Survey, Denver, Colorado, USA


Yan Zheng

Queens College, City University of New York, Flushing, New York, USA
Lamont-Doherty Earth Observatory of Columbia University, Palisades, New York, USA


Joseph D. Ortiz

Kent State University, Kent, Ohio, USA


Alexander van Geen

Lamont-Doherty Earth Observatory of Columbia University, Palisades, New York, USA


Abstract

Concentrations of organic carbon (orgC), cadmium (Cd), and molybdenum (Mo) were measured in two sediment cores raised from depths of 430 and 700 m within the oxygen-minimum zone (OMZ) off southern Baja California at a temporal resolution of ∼0.5 kyr over the past 52 kyr. These records are supplemented with diffuse spectral reflectance (DSR) measurements obtained on board ship soon after collection at a resolution of ∼0.05 kyr. In the core from 700 m depth, a component extracted from the DSR data and the three geochemical proxies generally vary in concert with each other and over a wide range (4–22% orgC; 1–40 mg/kg Cd; 5–120 mg/kg Mo). Intervals of increased orgC, Cd, and Mo accumulation generally correspond to warm periods recorded in the oxygen-isotopic composition of Greenland ice, with the exception of the Bolling/Allerod which is only weakly expressed off Baja California. Concentrations of the biogenic proxies are higher in the core from 430 m depth, but erratic sediment accumulation before 15 ka precludes dating of the older intervals that are laminated and contain elevated orgC, Cd, and Mo concentrations. The new data provide further evidence of an intimate teleconnection between global climate and the intensity of the OMZ and/or productivity along the western margin of North America. On the basis of a comparison with Cd and Mo records collected elsewhere in the region, we conclude that productivity may actually have varied off southern Baja California by no more than a factor of 2 over the past 52 kyr.

Received 7 November 2005; accepted 18 July 2006; published 25 November 2006.

Keywords: productivity; ventilation; Baja California.

Index Terms: 4901 Paleoceanography: Abrupt/rapid climate change (1605); 4924 Paleoceanography: Geochemical tracers; 4964 Paleoceanography: Upwelling (4279); 4926 Paleoceanography: Glacial; 4936 Paleoceanography: Interglacial.

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Citation: Dean, W. E., Y. Zheng, J. D. Ortiz, and A. van Geen (2006), Sediment Cd and Mo accumulation in the oxygen-minimum zone off western Baja California linked to global climate over the past 52 kyr, Paleoceanography, 21, PA4209, doi:10.1029/2005PA001239.