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G-Cubed: Geochemistry, Geophysics, Geosystems; an electronic journal of the Earth sciences

 

Keywords

  • Subduction factory
  • isotopic composition
  • geochemical cycles
  • hydrothermal processes

Index Terms

  • Geochemistry: Isotopic composition/chemistry
  • Geochemistry: Low-temperature geochemistry
Abstract
Cited By
 

Abstract

Stable isotopic composition of upper oceanic crust formed at a fast spreading ridge, ODP Site 801

Jeffrey C. Alt

Department of Geological Sciences, University of Michigan, Ann Arbor, Michigan 48109, USA

ODP Legs 129 and 185 sampled the upper 474 m of ∼170 Ma ocean crust in the western Pacific in order to investigate alteration processes in fast spread crust and to determine inputs to subduction. Fourteen composite bulk samples of altered upper oceanic crust from Site 801 have δ18O = 8.7–25.7‰, δD = −69.4‰ to −90.4‰, and δ13C = −2.7‰ to 1.8‰. The intensity of alteration and the amount of sediment within the basement decrease with depth, leading to corresponding decreases in δ18O and δD. A SUPER composite, constructed to estimate the bulk composition of the upper crust, has δ18O = 12.0‰, δD = −87.0‰, and δ13C = 0.7‰. Compared to core descriptions and geophysical logs, the SUPER composite contains too much 18O-rich sediment (δ18O = 25.7‰), and a corrected δ18O value of 10.8‰ is more reasonable for the upper crust at Site 801. These values are higher than those for other bulk upper oceanic basement sections (δ18O = 8.0–10.0‰) and result in part from: (1) intense low-temperature (<100°C) hydrothermal alteration of the upper 100 m of tholeiitic basement at Site 801 that may not be representative of material subducting in the western Pacific and (2) an aging effect, whereby progressive addition of 18O-rich secondary carbonate in veins and breccia cements contributed to the high bulk δ18O of this old upper crustal section.

Received 1 July 2002; accepted 28 February 2003; published 13 May 2003.

Citation: Alt, J. C. (2003), Stable isotopic composition of upper oceanic crust formed at a fast spreading ridge, ODP Site 801, Geochem. Geophys. Geosyst., 4(5), 8908, doi:10.1029/2002GC000400.

Cited By

Alt, Jeffrey C., and Wolfgang Bach (2006), Oxygen isotope composition of a section of lower oceanic crust, ODP Hole 735B, Geochem Geophys Geosyst, 7, Q12008, doi:10.1029/2006GC001385.

Wallmann, K. (2004), Impact of atmospheric CO2 and galactic cosmic radiation on Phanerozoic climate change and the marine ?18O record, Geochem Geophys Geosyst, 5, Q06004, doi:10.1029/2003GC000683.

Workman, R. K. (2004), Recycled metasomatized lithosphere as the origin of the Enriched Mantle II (EM2) end-member: Evidence from the Samoan Volcanic Chain, Geochem Geophys Geosyst, 5, Q04008, doi:10.1029/2003GC000623.