Abstract
Racemic mixtures of previously unknown chiral “tweezers” with a rigid asymmetrical diazocine bridge (Troger base) were synthesized on the basis of 4,4'-diaminodiphenyl sulfone. The Troger base was condensed with 2,4-dihydroxybenzaldehyde and 4-formylbenzoic acid to obtain new aromatic chelate cavities.
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Ziganshina, A.Y., Kazakova, E.K. & Habicher, W.D. 4,4'-Diaminodiphenyl Sulfone, a Substituted Troger Base, and Its Functionalization by the Amino Group. Russian Journal of General Chemistry 73, 1401–1405 (2003). https://doi.org/10.1023/B:RUGC.0000015987.59509.97
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DOI: https://doi.org/10.1023/B:RUGC.0000015987.59509.97