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Relaxor Behavior of (Sr0.8Ba0.2)TiO3 Ceramic Solid Solution Doped with Bismuth

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Abstract

The dielectric properties of (Sr0.8Ba0.2)1-1.5xBixTiO3 ceramics in the range 0 ≤ x ≤ 0.18 are investigated. A ferroelectric relaxor behavior is observed. The degree of the diffuseness and the relaxation of the phase transition increases as the Bi content increases. A random electric field is suggested to be responsible for the relaxor behavior observations. The dependence of the diffuseness on the grain size is presented.

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References

  1. G.A. Smolenskii, J. Phys. Soc. Jap., 28, (supplement), 26 (1970).

    Google Scholar 

  2. G.A. Smolenskii and A.I. Agranovskaya, Sov. Phys. Tech. Phys., 3, 1380 (1958).

    Google Scholar 

  3. N. Setter and L.E. Cross, J. Appl. Phys., 51, 4356 (1980).

    Google Scholar 

  4. G.A. Smolenskii, A.I. Agranovskaya, and V.A. Isupov, Sov. Phys. Solid State, 1, 907 (1959).

    Google Scholar 

  5. Liqin Zhou, P.M. Vilarinho, and J.L Baptista, Mater. Res. Bull., 29, 1193 (1994).

    Google Scholar 

  6. D. Hennings, A. Schnell, and G. Simon, J. Am. Ceram. Soc., 65, 539 (1982).

    Google Scholar 

  7. W.H. Payne and V.J. Tennery, J. Am. Ceram. Soc., 48, 413 (1965).

    Google Scholar 

  8. G.A. Smolenskii, V.A. Isupov, A.I. Agranovskaya, and S.N. Popov, Sov. Phys. Solid State, 2, 2584 (1961).

    Google Scholar 

  9. M.P. Harmer, A. Bhalla, B. Fox, and L.E. Cross, Mater. Lett., 2, 278 (1984).

    Google Scholar 

  10. C.A. Randall, D.J. Barber, and R.W. Whatmore, J. Microscopy, 145, 275 (1987).

    Google Scholar 

  11. J. Chen, H.M. Chan, and M.P. Harmer, J. Am. Ceram. Soc., 72, 593 (1989).

    Google Scholar 

  12. L.E. Cross, Ferroelectrics, 76, 241 (1987).

    Google Scholar 

  13. D. Viehland, J.F. Li, S.J. Jang, and L.E. Cross, Phys. Rev. B, 43, 8316 (1991).

    Google Scholar 

  14. V. Westphal, W. Kleemann, and M.D. Glinchuk, Phys. Rev. Lett., 68, 847 (1992).

    PubMed  Google Scholar 

  15. M.A. Akbas and P.K. Davies, J. Am. Ceram. Soc., 80, 2933 (1997).

    Google Scholar 

  16. K.A. Müller and H. Burkhard, Phys. Rev. B, 19, 3593 (1979).

    Google Scholar 

  17. J.G. Bednorz and K.A. Müller, Phys. Rev. Lett., 52, 2289 (1984).

    Google Scholar 

  18. G.I. Skanava, I.M. Ksendzov, V.A. Trigubenko, and V.G. Prokhvatilov, Sov. Phys. JEPT, 6, 250 (1958).

    Google Scholar 

  19. A. Cheng, Y. Zhi, P.M. Vilarinho, and J.L. Baptista, Phys. Rev. B, 57, 7403 (1998).

    Google Scholar 

  20. V.V. Lemanov, E.P. Smirnova, P.P. Syrnikov, and E.A. Tarakanov, Phys. Rev. B, 54, 3151 (1996).

    Google Scholar 

  21. Liqin Zhou, P.M. Vilarinho, and J.L. Baptista, J. Europ. Ceram. Soc., 19, 2015 (1999).

    Google Scholar 

  22. R.D. Shannon, Acta Cryst., A32, 751 (1976).

    Google Scholar 

  23. Liqin Zhou, P.M. Vilarinho, and J.L. Baptista, unpublished work.

  24. J. Toulouse, B.E. Vugmeister, and R. Pattnaik, Phys. Rev. Lett., 73, 3467 (1994).

    PubMed  Google Scholar 

  25. B.E. Vugmeister and M.D. Glinchuk, Rev. Mod. Phys., 62, 993 (1990).

    Google Scholar 

  26. H.L. Anderson, AIP Physics Vademecum (American Institute of Physics, New York, 1981), p. 294.

    Google Scholar 

  27. R.D. Shannon, J. Appl. Phys., 73, 348 (1993).

    Google Scholar 

  28. H. Kniepkamp, W. Heywang, and Z. Angew, Phys., 6, 385 (1954).

    Google Scholar 

  29. W.R. Buessen, L.E. Cross, and A.K. Goswami, J.Am. Ceram. Soc., 49, 33 (1966).

    Google Scholar 

  30. H.T. Martirena and J.C. Burfoot, J. Phys. C: Solid State Phys., 7, 3182 (1974).

    Google Scholar 

  31. N.M. Molokhia, M.A.A. Issa, and S.A. Nasser, J. Am. Ceram. Soc., 67, 289 (1984).

    Google Scholar 

  32. M.H. Frey and D.A. Payne, Phys. Rev. B, 54, 3158 (1996).

    Google Scholar 

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Zhou, L., Vilarinho, P. & Baptista, J. Relaxor Behavior of (Sr0.8Ba0.2)TiO3 Ceramic Solid Solution Doped with Bismuth. Journal of Electroceramics 5, 191–199 (2000). https://doi.org/10.1023/A:1026586226361

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  • DOI: https://doi.org/10.1023/A:1026586226361

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