Abstract
Conformational analysis of inclusion complexes of sodium 3-hydroxy-2-naphthalenecarboxylate with β-cyclodextrin and heptakis-(2,3,6-tri-o-methyl)-β-cyclodextrin in D2O was investigated by 1D and 2D 1HNMR measurements. The results show that part of the naphthyl group of sodium 3-hydroxy-2-naphthalenecarboxylate is situated in the 2,3-OH side of the β-cyclodextrin cavity asymmetrically while the whole naphthyl group is included in the heptakis-(2,3,6-tri-o-methyl)-β-cyclodextrin cavity with the caboxylate and hydroxy group close to the 6-OCH3 group.
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Yi, ZP., Hu, J. & Chen, HL. The Comparison of the Orientation of Sodium 3-Hydroxy-2-Naphthalenecarboxylate in the Cavity of β-Cyclodextrin and Heptakis-(2,3,6-Tri-O-Methyl)-β-Cyclodextrin. Journal of Inclusion Phenomena 45, 1–8 (2003). https://doi.org/10.1023/A:1023095817287
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DOI: https://doi.org/10.1023/A:1023095817287