Abstract
The interfacial structure and deformation between chlorinated polyolefin (CPO) adhesion promoter and automotive TPO substrates have been characterized with optical, scanning electron, and transmission electron microscopy techniques. The diffusion of rubber phase into the CPO layer was observed and an interphase thickness around 200 nm was obtained from TEM imaging. In some cases, a coherent failure of the adhesion promoter during the paint delamination was observed, which could be explained by the strong interphase formed due to the interfacial diffusion. It was found that baking at 120°C could significantly enhance the swelling of the rubber phase underneath the polypropylene-rich skin layer and the diffusion of the rubber phase into this layer. With decreasing molecular weight of PP homopolymer, the apparent interfacial strength measured by tensile cracking test increased, which was ascribed to the enhanced interfacial diffusion at low molecular weight. The deformation of materials near the interface during the paint delamination process was found to be more extensive in samples with higher interfacial adhesion.
Similar content being viewed by others
References
R. A. RYNTZ, Pro. Org. Coatings. 25 (1994) 73.
S. WADDINGTON and D. BRIGGS, Polymer Comm. 32 (1991) 506.
T. J. PRATER, S. L. KABERLINE, J. W. HOLUBKA and R. A. RYNTZ, J. Coat. Technol. 68 (1996) 83.
E. TOMASETTI, R. LEGRAS, B. HENRI-MAZEAUD and B. NYSTEN, Polymer 41 (2000) 6597.
H. R. MORRIS, B. MUNROE, R. A. RYNTZ and P. J. TREADO, Langmuir 14 (1998) 2426.
H. R. MORRIS, J. F. TURNER, B. MUNROE, R. A. RYNTZ and P. J. TREADO, ibid. 15 (1998) 2961.
E. TOMASETTI, S. VANDORPE, D. DAOUST, T. BOXUS, J. MARCHAND-BRYNAERT, C. POLEUNIS, P. BERTRAND, R. LEGRAS and P. G. ROUXHET, J. Adhesion Sci and Technol. 14 (2000) 779.
F. M. MIRABELLA, N. DIOH and C. G. ZIMBA, Polymer Eng. Sci. 40 (2000) 2000.
R. A. RYNTZ, Q. XIE and A. C. RAMAMURTHY, J. Coat. Technol. 67 (1995) 45.
H.-X. TANG and D. C. MARTIN, Polymer Eng. Sci. 41 (2001) 440.
D. MONTEZINOS, B. G. WELLS and J. L. BURNS, J. Polym. Sci.: Polym. Lett. Ed. 23 (1985) 421.
R. A. RYNTZ, Prog. Org Coat. 27 (1996) 241.
E. BOUCHER, J. P. FOLKERS, H. HERVET, L. LEGER and C. CRETON, Macromolecules 29 (1996) 774.
M. D. THOULESS, H. M. JENSEN and E. G. LINIGER, Proc. R. Soc. Lond. A 447 (1994) 271.
B.-M. ZHANG NEWBY, M. K. CHAUDHURY and H. R. BROWN, Science 269 (1995) 1407.
D. KONDOS and M. MAYO, in Proceedings of SPE Automotive TPO Global Conference (2000) p. 79.
E. BOUCHER, J. P. FOLKERS, H. HERVET, L. LEGER and C. CRETON, Macromolecules 29 (1996) 774.
A. F. TERZIS, D. N. THEODOROU and A. STROEKS, ibid. 35 (2002) 508.
Author information
Authors and Affiliations
Corresponding author
Additional information
An erratum to this article can be found at http://dx.doi.org/10.1023/A:1021877402407
Rights and permissions
About this article
Cite this article
Tang, H., Martin, D.C. Microstructural studies of interfacial deformation in painted thermoplastic polyolefins (TPOs). Journal of Materials Science 37, 4783–4791 (2002). https://doi.org/10.1023/A:1020858029040
Issue Date:
DOI: https://doi.org/10.1023/A:1020858029040