Skip to main content
Log in

Industrial Monitoring As a Source of Valuable Information on the Unit Process

  • Published:
Theoretical Foundations of Chemical Engineering Aims and scope Submit manuscript

Abstract

A new technique is suggested for processing industrial monitoring data for HCN synthesis by the oxidative ammonolysis of methane (Andrussow process). A mathematical model of the process is constructed using the Brandon method. Monitoring data processing by the suggested technique afforded results that are more reliable and informative than the results of laboratory experiments. The results obtained allowed the Andrussow process to be optimized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. Lux, H., Anorganisch-chemische Experimentierkunst, Leipzig: Barth, 1959, 2nd ed.

    Google Scholar 

  2. Mazin, V.D., Planirovanie izmerenii i obrabotka rezul'tatov (Measurement Design and Data Processing), St. Petersburg: S. Peterburg. Tekh. Univ., 1992.

    Google Scholar 

  3. Gmurman, V.E., Teoriya veroyatnostei i matematicheskaya statistika (Probability Theory and Mathematical Statistics), Moscow: Vysshaya Shkola, 1972.

    Google Scholar 

  4. Ivchenko, G.I. and Medvedev, Yu.I., Matematicheskaya statistika (Mathematical Statistics), Moscow: Vysshaya Shkola, 1984.

    Google Scholar 

  5. Bendat, J.S. and Piersol, A.G., Engineering Application of Correlation and Spectral Analysis, New York: Wiley, 1980.

    Google Scholar 

  6. Trusov, N.V., Grin', G.I., Loboiko, A.Ya., and Koshovets, N.V., Poluchenie sinil'noi kisloty po metodu Andrussova (Obtaining Hydrocyanic Acid by the Andrussow Method), Kharkov: Osnova, 1999.

    Google Scholar 

  7. Andrussow, L., Uber die katalytische Oxidation von Ammoniak–Methan–Gemischen zu Blausaure, Angew. Chem., 1935, vol. 48, no. 37, p. 593.

    Google Scholar 

  8. Adadurov, I.E., On Andrussow's Theory of the Catalytic Preparation of Hydrocyanic Acid, Ukr. Khim. Zh., 1936, vol. 11, no. 3, p. 237.

    Google Scholar 

  9. Atroshchenko, V.I., Obtaining Hydrocyanic Acid by the Andrussow Method, Tekhnologiya svyazannogo azota (Fixed Nitrogen Technology), Kharkov: Otd. Nauchn. Tekh. Inform., 1939, p. 26.

    Google Scholar 

  10. Wendlandt, R., Verfahren zur Herstellung von Cyanwasserstoff, Z. Electrochem. Angew. Chem., 1949, vol. 53, no. 5, p. 307.

    Google Scholar 

  11. Thomas, A., Recherches sur la synthese du gaz cyanhydrique a partir des melanges ammoniac–air–methane, Annu. Chim., 1949, vol. 4, no. 3/4, p. 258.

    Google Scholar 

  12. Andrussow, L., Synthese catalytique de l'acide cyanhydrigue et oxydation catalytique de l'ammoniak, Bull. Soc. Chim. Fr., 1951, no. 1/2, p. 45.

  13. Updegraff, N., Hydrogen Cyanide, Petroleum Refiner, 1953, vol. 32, no. 9, p. 197.

    Google Scholar 

  14. Maffezzonni, U., La fabrication de l'acide cyanhydrique partir du methane, de l'ammoniac et de l'air, Chem. Ind., 1953, vol. 69, no. 5, p. 842.

    Google Scholar 

  15. Costescu, D., Contributions a la synthese du gaz cyanhudrique a partir du methane de l'ammonique et de l'air, Acad. Repub. Pop. Rom. Stud. Cercet. Chim., 1957, vol. 56, no. 1, p. 91.

    Google Scholar 

  16. Bobkov, S.S., Producing Hydrocyanic Acid and Acrylonitrile, Khim. Nauka Prom–st., 1957, vol. 2, p. 34.

    Google Scholar 

  17. Henszelmann, F., Herstellung von Cyanwasserstoff aus Methan, Ammoniak und Sauerstoff, Magy. Kem. Lapja, 1958, vol. 13, no. 5/6, p. 183.

    Google Scholar 

  18. Krause, A., Die katalytische Synthese von HCN am Platinkontakt, Bull. Acad. Polon. Sci., 1960, vol. 8, no. 6, p. 301.

    Google Scholar 

  19. Sherwood, R., Synthesis of Hydrogen Cyanide by Autothermic Reactor, Ind. Eng. Chem. Fundam. Res., 1962, vol. 2, no. 2, p. 111.

    Google Scholar 

  20. Ryszawy, H. and Zygadlo, J., Zagadnienia konstrukcyjne reaktora do syntezy cyjanowodoru metoda Andrussowa, Przem. Chem., 1963, vol. 42, no. 6, p. 323.

    Google Scholar 

  21. Pan, B. and Roth, R., Optimization of Yield through Feed Composition, Ind. Eng. Chem. Proc. Des. Dev., 1968, vol. 7, no. 1, p. 53.

    Google Scholar 

  22. Bobkov, S.S. and Smirnov, S.K., Sinil'naya kislota (Hydrocyanic Acid), Moscow: Khimiya, 1970.

    Google Scholar 

  23. Koberstein, E., Modeling Process for HCN Synthesis from Methane and Ammonia, Ind. Eng. Chem. Pros. Des. Dev., 1973, vol. 12, no. 4, p. 444.

    Google Scholar 

  24. Baszynska, T., Seweryniak, M., and JaworskaGalas, Z., Postep w syntezie cyjanowodoru metoda Andrussowa, Przem. Chem., 1986, vol. 65, no. 12, p. 661.

    Google Scholar 

  25. Hasenberg, D. and Schmidt, L., HCN Synthesis from CH4 and NH3 on Platinum, J. Catal., 1987, vol. 104, no. 2, p. 441.

    Google Scholar 

  26. Atroshchenko, V.I. and Kargin, S.I., Tekhnologiya azotnoi kisloty (Nitric Acid Technology), Moscow: Khimiya, 1970.

    Google Scholar 

  27. Karavaev, M.M., Zasorin, A.P., and Kleshchev, N.F., Kataliticheskoe okislenie ammiaka (Catalytic Oxidation of Ammonia), Moscow: Khimiya, 1970.

    Google Scholar 

  28. Kafarov, V.V., Metody kibernetiki v khimii i khimicheskoi tekhnologii (Methods of Cybernetics in Chemistry and Chemical Engineering), Moscow: Khimiya, 1976.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Trusov, N.V., Grin', G.I. & Prezhdo, V.V. Industrial Monitoring As a Source of Valuable Information on the Unit Process. Theoretical Foundations of Chemical Engineering 36, 505–510 (2002). https://doi.org/10.1023/A:1020690232025

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020690232025

Keywords

Navigation