Abstract
A new technique is suggested for processing industrial monitoring data for HCN synthesis by the oxidative ammonolysis of methane (Andrussow process). A mathematical model of the process is constructed using the Brandon method. Monitoring data processing by the suggested technique afforded results that are more reliable and informative than the results of laboratory experiments. The results obtained allowed the Andrussow process to be optimized.
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REFERENCES
Lux, H., Anorganisch-chemische Experimentierkunst, Leipzig: Barth, 1959, 2nd ed.
Mazin, V.D., Planirovanie izmerenii i obrabotka rezul'tatov (Measurement Design and Data Processing), St. Petersburg: S. Peterburg. Tekh. Univ., 1992.
Gmurman, V.E., Teoriya veroyatnostei i matematicheskaya statistika (Probability Theory and Mathematical Statistics), Moscow: Vysshaya Shkola, 1972.
Ivchenko, G.I. and Medvedev, Yu.I., Matematicheskaya statistika (Mathematical Statistics), Moscow: Vysshaya Shkola, 1984.
Bendat, J.S. and Piersol, A.G., Engineering Application of Correlation and Spectral Analysis, New York: Wiley, 1980.
Trusov, N.V., Grin', G.I., Loboiko, A.Ya., and Koshovets, N.V., Poluchenie sinil'noi kisloty po metodu Andrussova (Obtaining Hydrocyanic Acid by the Andrussow Method), Kharkov: Osnova, 1999.
Andrussow, L., Uber die katalytische Oxidation von Ammoniak–Methan–Gemischen zu Blausaure, Angew. Chem., 1935, vol. 48, no. 37, p. 593.
Adadurov, I.E., On Andrussow's Theory of the Catalytic Preparation of Hydrocyanic Acid, Ukr. Khim. Zh., 1936, vol. 11, no. 3, p. 237.
Atroshchenko, V.I., Obtaining Hydrocyanic Acid by the Andrussow Method, Tekhnologiya svyazannogo azota (Fixed Nitrogen Technology), Kharkov: Otd. Nauchn. Tekh. Inform., 1939, p. 26.
Wendlandt, R., Verfahren zur Herstellung von Cyanwasserstoff, Z. Electrochem. Angew. Chem., 1949, vol. 53, no. 5, p. 307.
Thomas, A., Recherches sur la synthese du gaz cyanhydrique a partir des melanges ammoniac–air–methane, Annu. Chim., 1949, vol. 4, no. 3/4, p. 258.
Andrussow, L., Synthese catalytique de l'acide cyanhydrigue et oxydation catalytique de l'ammoniak, Bull. Soc. Chim. Fr., 1951, no. 1/2, p. 45.
Updegraff, N., Hydrogen Cyanide, Petroleum Refiner, 1953, vol. 32, no. 9, p. 197.
Maffezzonni, U., La fabrication de l'acide cyanhydrique partir du methane, de l'ammoniac et de l'air, Chem. Ind., 1953, vol. 69, no. 5, p. 842.
Costescu, D., Contributions a la synthese du gaz cyanhudrique a partir du methane de l'ammonique et de l'air, Acad. Repub. Pop. Rom. Stud. Cercet. Chim., 1957, vol. 56, no. 1, p. 91.
Bobkov, S.S., Producing Hydrocyanic Acid and Acrylonitrile, Khim. Nauka Prom–st., 1957, vol. 2, p. 34.
Henszelmann, F., Herstellung von Cyanwasserstoff aus Methan, Ammoniak und Sauerstoff, Magy. Kem. Lapja, 1958, vol. 13, no. 5/6, p. 183.
Krause, A., Die katalytische Synthese von HCN am Platinkontakt, Bull. Acad. Polon. Sci., 1960, vol. 8, no. 6, p. 301.
Sherwood, R., Synthesis of Hydrogen Cyanide by Autothermic Reactor, Ind. Eng. Chem. Fundam. Res., 1962, vol. 2, no. 2, p. 111.
Ryszawy, H. and Zygadlo, J., Zagadnienia konstrukcyjne reaktora do syntezy cyjanowodoru metoda Andrussowa, Przem. Chem., 1963, vol. 42, no. 6, p. 323.
Pan, B. and Roth, R., Optimization of Yield through Feed Composition, Ind. Eng. Chem. Proc. Des. Dev., 1968, vol. 7, no. 1, p. 53.
Bobkov, S.S. and Smirnov, S.K., Sinil'naya kislota (Hydrocyanic Acid), Moscow: Khimiya, 1970.
Koberstein, E., Modeling Process for HCN Synthesis from Methane and Ammonia, Ind. Eng. Chem. Pros. Des. Dev., 1973, vol. 12, no. 4, p. 444.
Baszynska, T., Seweryniak, M., and JaworskaGalas, Z., Postep w syntezie cyjanowodoru metoda Andrussowa, Przem. Chem., 1986, vol. 65, no. 12, p. 661.
Hasenberg, D. and Schmidt, L., HCN Synthesis from CH4 and NH3 on Platinum, J. Catal., 1987, vol. 104, no. 2, p. 441.
Atroshchenko, V.I. and Kargin, S.I., Tekhnologiya azotnoi kisloty (Nitric Acid Technology), Moscow: Khimiya, 1970.
Karavaev, M.M., Zasorin, A.P., and Kleshchev, N.F., Kataliticheskoe okislenie ammiaka (Catalytic Oxidation of Ammonia), Moscow: Khimiya, 1970.
Kafarov, V.V., Metody kibernetiki v khimii i khimicheskoi tekhnologii (Methods of Cybernetics in Chemistry and Chemical Engineering), Moscow: Khimiya, 1976.
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Trusov, N.V., Grin', G.I. & Prezhdo, V.V. Industrial Monitoring As a Source of Valuable Information on the Unit Process. Theoretical Foundations of Chemical Engineering 36, 505–510 (2002). https://doi.org/10.1023/A:1020690232025
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DOI: https://doi.org/10.1023/A:1020690232025