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Induced Silver Ion Transfer across the Aqueous Solution/Organic Phase Interface in the Presence of Sulfur-Containing Ionophores: Conceptual Models and Analytical Applications

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Abstract

The voltammetric behavior of silver at the water/nitrobenzene and water/1,2-dichloroethane interfaces was studied in the presence of diphenylthiourea and O,O-dihexyl dithiophosphates. The composition of the complexes and the standard potentials of their transfer were determined, and the standard energies and stability constants of the complexes in the membrane phase were calculated. The selectivity and sensitivity of voltammetric methods of analysis at the interface of immiscible electrolytes were discussed.

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Authors and Affiliations

  1. Mendeleev University of Chemical Engineering, Miusskaya pl. 9, Moscow, 125190, Russia

    O. M. Petrukhin, A. A. Dunaeva, N. V. Kolycheva & E. V. Shipulo

  2. Luter University, Halle-Wittenberg, D-06099, Halle, Germany

    S. Wilke & H. Müller

  3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova 28, Moscow, 117813, Russia

    G. K. Genkina & T. A. Mastryukova

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  1. O. M. Petrukhin
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  2. A. A. Dunaeva
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Petrukhin, O.M., Dunaeva, A.A., Wilke, S. et al. Induced Silver Ion Transfer across the Aqueous Solution/Organic Phase Interface in the Presence of Sulfur-Containing Ionophores: Conceptual Models and Analytical Applications. Journal of Analytical Chemistry 57, 240–247 (2002). https://doi.org/10.1023/A:1014448400258

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