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Mössbauer Studies in the Mechanochemistry of Spinel Ferrites

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Journal of Materials Synthesis and Processing

Abstract

Mössbauer spectroscopy can provide information on a large variety of mechanochemical processes in solids. In this overview, selected examples are presented of Mössbauer studies of homogeneous and heterogeneous mechanochemical reactions in spinel ferrites. Several interesting features are involved in the work, e.g., mechanically induced cation redistributions, changes of nearest-neighbor configurations, superparamagnetic relaxation, spin-canting effects, as well as formation and redox reactions. The considerable literature on mechanically treated spinel ferrites is reviewed. Despite numerous efforts, the understanding of the nonequilibrium mechanochemical processes in spinel ferrites is considered to be far from complete.

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Authors and Affiliations

  1. nstitute of Geotechnics, Slovak Academy of Sciences, SK-04353, Košice, Slovak Republic

    V. Šepelák

  2. Institute of Physical and Theoretical Chemistry, Technical University of Braunschweig, D-38106, Braunschweig, Germany

    K. D. Becker

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  1. V. Šepelák
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  2. K. D. Becker
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Šepelák, V., Becker, K.D. Mössbauer Studies in the Mechanochemistry of Spinel Ferrites. Journal of Materials Synthesis and Processing 8, 155–166 (2000). https://doi.org/10.1023/A:1011355908538

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