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Kinetics of Thermal Decomposition of Copper(II) Acetate Monohydrate

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Abstract

The thermal decomposition of copper(II) acetate monohydrate was studied in air and nitrogen atmospheres by means of DTA-TG and SEM measurements. The kinetics of the thermal decomposition steps in air was studied by using isothermal and non-isothermal thermogravimetric techniques. The results are discussed in terms of various reaction interface models and different techniques of computational analysis of non-isothermal data. The activation parameters, calculated by using a composite method of integral analysis of non-isothermal data, revealed not only their independence from the heating rate and fractional reaction, but also a better correlation and agreement with the results obtained under isothermal conditions.

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Authors and Affiliations

  1. Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, P.O. Box 9028, Saudi Arabia

    A. Y Obaid, A. O. Alyoubi, A. A. Samarkandy, S. A. Al-Thabaiti, S. S. Al-Juaid, A. A. El-Bellihi & El-H. M. Deifallah

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  1. A. Y Obaid
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  2. A. O. Alyoubi
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  3. A. A. Samarkandy
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  4. S. A. Al-Thabaiti
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  5. S. S. Al-Juaid
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  6. A. A. El-Bellihi
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  7. El-H. M. Deifallah
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Obaid, A.Y., Alyoubi, A.O., Samarkandy, A.A. et al. Kinetics of Thermal Decomposition of Copper(II) Acetate Monohydrate. Journal of Thermal Analysis and Calorimetry 61, 985–994 (2000). https://doi.org/10.1023/A:1010179532267

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