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Guest–Host Interactions in Hofmann-Td-type Aniline Clathrates: IR Spectral Study

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Abstract

Synthesis and IR spectra of novel Hofmann-T d -type aniline clathrates, M(NH3)2Zn(CN)4· 2C6H5NH2 (M = Zn or Cd) are reported for the first time. All the vibrational modes of aniline are characterised. The shifts in ν a (NH2) and ν s (NH2) reveal hydrogen bonding between the NH2 group of aniline and the cyanide group of the host lattice to be stronger than in Hofmann-type aniline clathrates. However, the out of plane deformation mode of aniline indicates absence of hydrogen bonding between ammonia and the π-cloud of the aniline ring. The related aniline clathrates with bridging Cd(CN)4 M(NH3)2Cd(CN)4· 2C6H5NH2 (M=Zn or Cd), exhibit similar behaviour.

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Authors and Affiliations

  1. School of Chemistry, Madurai Kamaraj University, Madurai, 625 021, India

    R. Murugesan

  2. Department of Chemistry, Thiagarajar College, Madurai, 625 009, India

    A. Thamaraichelvan

  3. Department of Chemistry, VHNSN College, Virudhunagar, 626 001, India

    P. Sami

Authors
  1. R. Murugesan
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  2. A. Thamaraichelvan
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  3. P. Sami
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Murugesan, R., Thamaraichelvan, A. & Sami, P. Guest–Host Interactions in Hofmann-Td-type Aniline Clathrates: IR Spectral Study. Journal of Inclusion Phenomena 34, 235–243 (1999). https://doi.org/10.1023/A:1008084711758

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