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Abstract

The sorption of maltol (3-hydroxy-2-methyl-4-pyrone) by Fe-montmorillonite from aqueous solutions is pH dependent. IR and Mössbauer spectroscopy indicate bonding of maltol oxygen ligands to the interlayer Fe(III). Simultaneously maltol releases part of the Fe(III) into the solution. The interaction of the Fe-maltolato complex with Na-montmorillonite occurs by ion exchange.

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References

  1. M.M. Finnegan, S.J. Rettig, and C. Orvig: J. Am. Chem. Soc. 108, 5033 (1986).

    Google Scholar 

  2. H. Luo, S.J. Rettig, and C. Orvig: Inorg. Chem. 32, 4491 (1993).

    Google Scholar 

  3. M.M. Finnegan, T.G. Lutz, W.O. Nelson, A. Smith, and C. Orvig: Inorg. Chem. 26, 2171 (1987).

    Google Scholar 

  4. J. Šima, B. Chochulová, M. Veverka, J. Makáňová, H. HajŠelová, and A. Bradiaková: Polish J. Chem. 67, 1369 (1993).

    Google Scholar 

  5. K. Jesenák and V.Š. Fajnor: Mineralia Slov. 27, 221 (1995).

    Google Scholar 

  6. R. Herrera and M. Peech: Soil Sci. Soc. Am. Proc. 34, 740 (1970).

    Google Scholar 

  7. T.G. Spiro, S.A. Allerton, J. Renner, A. Terzis, R. Bils, and P. Saltman: J. Am. Chem. Soc. 88, 2721 (1966).

    Google Scholar 

  8. W.H. Hendershot and M. Duquette: Soil Sci. Soc. Am. J. 50, 605 (1986).

    Google Scholar 

  9. R. Přibyl: Komplexometrie, pp.143–149, SNTL Prague (1977).

  10. R.A. Brand: NORMOS Program, Interval Report, Universität Duisburg (1987).

  11. A. Stefanović, J. Havel, and L. Sommer: Collect. Czech. Chem. Commun. 12, 4198 (1968).

    Google Scholar 

  12. M.T. Ahmet, C.S. Frampton, and J. Silver: J. Chem. Soc., Dalton Trans. 1159 (1988).

  13. A.R. Katritzky and R.A. Jones: J. Chem. Soc. 2947 (1960).

  14. A.R. Katritzky and R.A. Jones: Spectrochim. Acta 17, 64 (1961).

    Google Scholar 

  15. T.A. Annan, C. Peppe, and D.G. Tuck: Can. J. Chem. 68, 1598 (1990).

    Google Scholar 

  16. L. Heller-Kallai, S. Yariv, and M. Riemer: Clay Minerals 10, 35 (1973).

    Google Scholar 

  17. J.E. Amonette and D. Rai: Clays Clay Minerals 38, 129 (1990).

    Google Scholar 

  18. V. Luca and C.M. Cardile: Clays Clay Minerals 37, 375 (1989).

    Google Scholar 

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Luptáková, V., Sitek, J. & Tóth, I. Interaction of Montmorillonite with Maltol. Journal of Inclusion Phenomena 34, 97–104 (1999). https://doi.org/10.1023/A:1008068102633

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  • DOI: https://doi.org/10.1023/A:1008068102633

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