Abstract
A novel vic-dioxime, 1,2 dihydroxyimino-1-p-tolyl-3-aza-6-morpholine heptane (LH2) was prepared by reacting anti-p-tolylchloroglyoxime with 4-(3-aminopropyl)morpholine in absolute THF. Mononuclear complexes with a metal–ligand ratio of 1:2 were prepared using CoII, CuII and NiII salts. The ligand and its complexes were characterized by elemental analyses, FT-IR, u.v.–vis., 1H- and 13C-n.m.r. spectra, magnetic susceptibility measurements, thermogravimetric analyses (t.g.a.), and by cyclic voltammetry.
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Tas, E., Ulusoy, M., Guler, M. et al. Synthesis, characterization and redox properties of a new vic-dioxime and its transition metal complexes. Transition Metal Chemistry 29, 180–184 (2004). https://doi.org/10.1023/B:TMCH.0000019417.35877.b9
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DOI: https://doi.org/10.1023/B:TMCH.0000019417.35877.b9