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Crystal structure of (ethylenediammonium-N,N′-di-3-propanoic acid) tetrachloropalladate(II) complex

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Abstract

The title compound was obtained by a synthesis from ethylenediamine-N,N′-di-3-propanoic acid dihydrochloride (H2eddp⋅2HCl) and potassium hexachloropalladate(IV) (molar ratio 1:1, in water). Its structure has been determined by single-crystal X-ray diffraction: monoclinic space group P21/n, a = 8.198(1), b = 10.282(1), c = 9.080(1) Å, β = 103.62(1)°, V = 743.9(2) Å3, and Z = 2. The dianionic complex has a square-planar coordination geometry with four chloro ligands, and ethylenediamine-N,N′-di-3-propanoic acid as dication in the second coordination sphere. This is the first reported Pd(II) structure with uncoordinated H2eddp.

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Authors and Affiliations

  1. Faculty of Chemistry, University of Belgrade, Studentski trg 16, P.O. Box 158, 11001, Belgrade, Serbia and, Montenegro

    G.N. Kaluđerović, F.W. Heinemann, N.Ž. Knežević, S.R. Trifunović & T. J. Sabo

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  1. G.N. Kaluđerović
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  2. F.W. Heinemann
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  3. N.Ž. Knežević
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  4. S.R. Trifunović
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  5. T. J. Sabo
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Kaluđerović, G., Heinemann, F., Knežević, N. et al. Crystal structure of (ethylenediammonium-N,N′-di-3-propanoic acid) tetrachloropalladate(II) complex. Journal of Chemical Crystallography 34, 185–189 (2004). https://doi.org/10.1023/B:JOCC.0000021562.41341.75

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  • DOI: https://doi.org/10.1023/B:JOCC.0000021562.41341.75

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