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Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane

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Abstract

Silsesquioxanes (SSO) were synthesized by the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane (GPMS). Their structure was characterized by FTIR and NMR (1H, 13C, 29Si), and the molar mass distribution was determined by UV-MALDI-TOF MS. Films were synthesized by adding the stoichiometric amount of ethylenediamine to SSO solutions in ethanol, dip-coating over glass substrates, and curing using an appropriate thermal cycle. The transmittance of the films was measured by UV-VIS-NIR scanning spectrophotometer (SSP); hardness and modulus were determined with the continuous stiffness measurement (CSM) technique of an instrumented-indentation testing (IIT) device. The effect of the substrate on the coating system was analyzed.

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Authors and Affiliations

  1. Department of Applied Chemistry, Harbin Institute of Technology (HIT), Harbin, 150001, People's Republic of China

    Lijiang Hu, Xingwen Zhang, Hong You, Yan Liu & Dezhi Sun

  2. Department of Applied Chemistry, Harbin Institute of Technology (HIT), Harbin, 150001, People's Republic of China

    Hao Zhang

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  1. Lijiang Hu
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  2. Xingwen Zhang
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  3. Hong You
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  4. Yan Liu
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  6. Dezhi Sun
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Correspondence to Lijiang Hu.

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Hu, L., Zhang, X., You, H. et al. Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane. Journal of Materials Science 39, 1331–1335 (2004). https://doi.org/10.1023/B:JMSC.0000013893.58417.7e

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  • DOI: https://doi.org/10.1023/B:JMSC.0000013893.58417.7e

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