Abstract
For the liquid-phase partial hydrogenation of benzene at 483 K, the selectivity toward cyclohexene was greatly improved upon treating rare earth nitride with ammonia. For YbN obtained by thermal decomposition of Yb(NH2)2 at 1173 K, the selectivity of the NH3-treated YbN was 75%, in contrast to nil for the untreated YbN.
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References
The Role of Rare Earths in Catalysis, in: Handbook on the Physics and Chemistry of Rare Earths, Vol 29, eds. K.A. Gschneidner Jr. and L. Eyring (North-Holland, Amsterdam, 2000).
(a)W.J. Peer and J.J. Lagowski, J. Phys. Chem. 84 (1980) 1110; (b) J.C. Thompson, Electrons in Liquid Ammonia (Clarendon Press, Oxford, 1976).
H. Imamura, in: Handbook on the Physics and Chemistry of Rare Earths, Vol. 29, eds. K.A. Gschneidner Jr. and L. Eyring (North-Holland, Amsterdam, 2000), Ch. 182.
H. Imamura, T. Kumai, K. Nishimura, T. Nuruyu and Y. Sakata, Catal. Lett. 82 (2002) 69.
H. Imamura, K. Nishimura, K. Sumioki, M. Fujimoto and Y. Sakata, Chem. Lett. (2001) 450.
H. Imamura, T. Konishi, Y. Sakata and S. Tsuchiya, J. Chem. Soc. Chem. Commun. (1993) 1852; J. Chem. Soc. Faraday Trans. 88 (1992) 2251.
(a)H. Nagahara, M. Ono, M. Konishi and Y. Fukuoka, Appl. Surf. Sci. 121/122 (1997) 448; (b) H. Nagahara, M. Ono and Y. Fukuoka, Stud. Surf. Sci. Catal. 92 (1995) 375; (c) F. Doebert and J. Gaube, Catal. Lett. 31 (1995) 431; (d) M. Soede, E.J.A.X. van de Sandt, M. Makkee and J.J.F. Scholten, Stud. Surf. Sci. Catal. 78 (1993) 345; (e) F. Mizukami, S. Niwa, S. Ohkawa and A. Katayama, Stud. Surf. Sci. Catal. 78 (1993) 337; (f) J. Struijk, M. D'Angremond, W.J.M. Lucas-De Regt and J.J.F. Scholten, Appl. Catal. A 83 (1992) 263; (g) Y. Fukuoka and H. Nagahara, Prepr. Am. Chem. Soc., Div. Pet. Chem. 36 (1991) 5481.
H. Imamura, T. Konishi, E. Suda, Y. Sakata and S. Tsuchiya, Bull. Chem. Soc. Jpn. 69 (1996) 77.
(a)K. Howell and L.L. Pytlewski, J. Less-Common Met. 19 (1969) 399; (b) S. Salot and J.C. Warf, J. Am. Chem. Soc. 90 (1968) 1932; (c) R. Juza and C. Hadendeldt, Naturwissenschaften 55 (1968) 229.
C. Hadenfeldt, H. Jacob's and R. Juza, Z. Anorg. Allg. Chem. 144 (1970) 379.
T. Baba, S. Hikita, R. Koide, Y. Ono, T. Hanada, T. Tanaka and S. Yoshida, J. Chem. Soc. Faraday Trans. 89 (1993) 3177.
H. Imamura, K. Nishimura, T. Yoshimura, H. Yoshimochi, M. Ueno, Y. Sakata and S. Tsuchiya, J. Mol. Catal. A 165 (2001) 189.
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Imamura, H., Nuruyu, T., Kawasaki, T. et al. Improvement of Selectivity for Partial Hydrogenation of Benzene by Rare Earth Nitride Upon NH3 Treatment. Catalysis Letters 96, 185–187 (2004). https://doi.org/10.1023/B:CATL.0000030118.52064.39
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DOI: https://doi.org/10.1023/B:CATL.0000030118.52064.39