Skip to main content
SpringerLink
Log in

Synthesis and characterization of organophosphoryl polyoxotungstates [RP(O)]2Xn+W11O39 (8−n)− (Xn+ = P5+, Si4+, Ge4+, Ga3+)

  • Published:
Transition Metal Chemistry Aims and scope Submit manuscript

Abstract

In the presence of n-Bu4NBr acting as phase-transfer reagent, n-Bu4N+ salts of organophosphoryl polyoxotungstate derivatives [RP(O)]2Xn+W11O39 (8−n)− [R = PhCH2CH2P(O), X = P, Si; R = C6H11P(O); X = Ge, Ga] have been prepared and characterized by elemental analysis, i.r., 31P- and 183W-n.m.r. spectroscopy. According to the elemental analysis and spectroscopic data, the hybrid anions consist of an α-[XW11O39] framework on which are grafted two equivalent organophosphoryl groups through P—O—W bridges; these new species still retain the Keggin structure. The six-line 183W spectrum indicates that hybrid anions possess C s symmetry in MeCN.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M.P. Pope and A. Müller, Angew. Chem. Int. Ed. Engl., 30, 34 (1991).

    Google Scholar 

  2. P. Gouzerh and A. Proust, Chem. Rev., 98, 77 (1998).

    Google Scholar 

  3. G.S. Kim, K.S. Hagen and C.L. Hill, Inorg. Chem., 31, 5316 (1992).

    Google Scholar 

  4. M. Weeks, C.L. Hill and R.F. Schinazi, J. Med. Chem., 35, 1216 (1992).

    Google Scholar 

  5. J.T. Rhule, C.L. Hill and D.A. Judd, Chem. Rev., 98, 327 (1998).

    Google Scholar 

  6. Z.G. Sun, Q. Liu and J.F. Liu, Main Group Met. Chem., 23, 189 (2000).

    Google Scholar 

  7. Z.G. Sun, Q. Liu and J.F. Liu, Inorg. Chem. Commun., 3, 328 (2000).

    Google Scholar 

  8. Z.G. Sun, Q. Liu and J.F. Liu, Transition Met. Chem., 25, 374 (2000).

    Google Scholar 

  9. Z.G. Sun, S.M. Yue, Q. Liu and J.F. Liu, Chem. J. Chinese Univ., 21, 24 (2000).

    Google Scholar 

  10. C.R. Mayer and R. Thouvenot, J. Chem. Soc., Dalton Trans., 7 (1998).

  11. C.R. Mayer, P. Herson and R. Thouvenot, Inorg. Chem., 38, 6152 (1999).

    Google Scholar 

  12. C. Brevard, R. Schimpf, G. Tourne and C.M. Tourne, J. Am. Chem. Soc., 105, 7059 (1983).

    Google Scholar 

  13. N. Haraguchi, Y. Okaue, T. Isobe and Y. Matsuda, Inorg. Chem., 33, 1015 (1994).

    Google Scholar 

  14. J.O. Clayton and W.L. Jensen, J. Am. Chem. Soc., 70, 3880 (1948).

    Google Scholar 

  15. W.L. Jensen and C.R. Noller, J. Am. Chem. Soc., 71, 2384 (1949).

    Google Scholar 

  16. O.A. Gansow, R.K.C. Ho and W.G. Klemperer, J. Organometal Chem., 187, C27 (1980).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Liaoning Normal University, Dalian, 116029, P.R. China

    Zhen-Gang Sun, Zai-Ming Zhu & Wan-Sheng You

  2. Department of Chemistry, Northeast Normal University, Changchun, 130024, P.R. China

    Jing-Fu Liu

Authors
  1. Zhen-Gang Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Zai-Ming Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Wan-Sheng You
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jing-Fu Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sun, ZG., Zhu, ZM., You, WS. et al. Synthesis and characterization of organophosphoryl polyoxotungstates [RP(O)]2Xn+W11O39 (8−n)− (Xn+ = P5+, Si4+, Ge4+, Ga3+). Transition Metal Chemistry 28, 849–851 (2003). https://doi.org/10.1023/A:1026385320218

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1026385320218

Keywords

Search

Navigation