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Activated-Carbon-Heterogenized [PdCl2(NH2(CH2)12CH3)2] for the Selective Hydrogenation of 1-Heptyne

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Abstract

The complex [PdCl2(NH2(CH2)12CH3)2] has been heterogenized on two different activated carbons and tested as a catalyst for the semihydrogenation of 1-heptyne. The results are compared with those previously reported with the γ-Al2O3-supported complex. An important effect of the support porosity has been found. The location of the complex in the narrow pores induces shape selectivity. The effect of the support in concentrating the substrate close to the active species has been observed. A very active and selective catalyst has been prepared using an essentially microporous carbon.

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Authors and Affiliations

  1. Química Inorgánica-INCAPE, Facultad de Ingeniería Química, Universidad Nacional del Litoral-CONICET, Santiago del Estero 2829, 3000, Santa Fe, Argentina

    P.C. L'Argentière, M.E. Quiroga, D.A. Liprandi & E.A. Cagnola

  2. Departamento de Química Inorgánica, Universidad de Alicante, Ap. 99, Alicante, Spain

    M.C. Román-Martínez, J.A. Díaz-Auñón & C. Salinas-Martínez de Lecea

Authors
  1. P.C. L'Argentière
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  2. M.E. Quiroga
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  3. D.A. Liprandi
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  4. E.A. Cagnola
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  5. M.C. Román-Martínez
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  6. J.A. Díaz-Auñón
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  7. C. Salinas-Martínez de Lecea
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Correspondence to M.C. Román-Martínez.

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L'Argentière, P., Quiroga, M., Liprandi, D. et al. Activated-Carbon-Heterogenized [PdCl2(NH2(CH2)12CH3)2] for the Selective Hydrogenation of 1-Heptyne. Catalysis Letters 87, 97–101 (2003). https://doi.org/10.1023/A:1022869513974

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