Abstract
An effective method of reducing the mass of a lead acid battery is to replace the lead with a less dense electrical conductor such as carbon. The application of a thin layer of lead onto the surface of carbon fibres can improve the electrical and mechanical properties of the bond between the fibre and battery active material. Under-potential deposition was used to apply a thin layer of lead onto carbon fibre tows. The efficiency of this process using a number of different electrolytes and voltage ranges was assessed. X-ray photoelectron spectroscopy and secondary ion mass spectroscopy were used to evaluate the deposition process. Lead was successfully deposited onto the surface of the fibres at a potential of approximately 262 mV using the electrolyte consisting of 0.1 M HCIO4 and 0.01 M Pb(OAC)2.
Similar content being viewed by others
References
R. EVANS, PhD thesis, Department of Chemistry, University of Cardiff, 1993.
H. HOTOP and W. C. WINEBERGER, J. Phys Chem. Ref. Data 4 (1975) 539.
C. R. BRUNDLE, C. A. EVANS Jr. and S. WILSON, “Encyclopedia of Materials Characterisation” (Butterworth-Heinemann, 1992), p. 198.
J. P. EBERHART, “Structural and Chemical Analysis of Materials” (Wiley and Sons, U.K., 1991), p. 372.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lawrence, E.L., Ball, R.J., Evans, R. et al. Under potential deposition of lead onto carbon fibres for use in lead/acid battery applications. Journal of Materials Science 37, 4517–4520 (2002). https://doi.org/10.1023/A:1020615424980
Issue Date:
DOI: https://doi.org/10.1023/A:1020615424980