Abstract
In the development of a new hybrid adsorption–catalytic method it was shown that the selective adsorption isolation of components can be combined with their catalytic determination directly on the adsorbent. To provide theoretical grounds and find fields of the application of the new method, the effect of the support matrix on the rate of catalytic (enzymatic and indicator) reactions was studied. The changes in the performance characteristics of procedures for determining inorganic and organic substances directly on the adsorbent with respect to those of procedures for determining in solutions were analyzed. It was proved that the development of catalytic test procedures with the visual detection of the analytical signal is expedient.
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REFERENCES
Zolotov, Yu.A., Vestn. Ross. Akad. Nauk, 1997, vol. 67, no. 6, p. 508.
Zolotov, Yu.A., Khim. Promyshlennost' (Moscow), 1997, no. 6, p. 48.
Babko, A.K. and Maksimenko, T.S., Zh. Anal. Khim., 1967, vol. 22, no. 4, p. 570.
Mueller, H., CRC Crit. Rev. Anal. Chem., 1982, vol. 13, p. 313.
Tikhonova, L.P., Bakay, E.A., Prokhorenko, E.P., Tarkovskaya, I.A., and Sharkovskaya, I.P., “Kinetics in Analytical Chemistry,” Moscow, 1995, p. 224.
Beklemishev, M.K., Petrova, Yu.Yu., and Dolmanova, I.F., Analyst (Cambridge, UK), 1999, vol. 127, p. 1523.
Kapanadze, A.L., Beklemishev, M.K., and Dolmanova, I.F., Zh. Anal. Khim., 1999, vol. 54, p. 1182.
Muginova, S.V., Veselova, I.A., and Shekhovtsova, T.N., Zh. Prikl. Khim. (St. Petersburg), 1999, vol. 72, no. 5, p. 803.
Craven, R., J. Chem. Soc., 1931, no. 6, p. 1605.
King, T.J. and Newall, C.E., J. Chem. Soc., 1965, no. 2, p. 974.
Beklemishev, M.K., Stoyan, T.A., and Dolmanova, I.F., Analyst (Cambridge, UK), 1997, vol. 122, p. 1161.
Petrova, Yu.Yu., Beklemishev, M.K., Bazhanova, N.A., Druzhinin, A.A., and Dolmanova, I.F., Zh. Anal. Khim., 2000, vol. 55, no. 3, p. 318.
Beklemishev, M.K., Stoyan, T.A., and Dolmanova, I.F., Fresenius' J. Anal. Chem., 2000, vol. 367, p. 17.
Beklemishev, M.K., Petrova, Yu.Yu., and Dolmanova, I.F., Mikrochim. Acta, 2001, vol. 136, p. 35.
Beklemishev, M.K., Kapanadze, A.L., Bakhilina, N.V., and Dolmanova, I.F., Talanta, 2000, vol. 51, p. 389.
Petrova, Yu.Yu. and Beklemishev, M.K., Abstracts of Papers, Mezhdunarodnyi simpozium “Meditsina i okhrana zdorov'ya-98” (Int. Symp. “Medicine and Health Protection-98”), Tyumen, 1998, p. 279.
Shekhovtsova, T.N., Muginova, S.V., and Bagirova, N.A., Anal. Chim. Acta, 1997, vol. 344, p. 145.
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Dolmanova, I.F., Shekhovtsova, T.N. & Beklemishev, M.K. Adsorption–Catalytic Test Methods. Journal of Analytical Chemistry 57, 882–889 (2002). https://doi.org/10.1023/A:1020466723519
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DOI: https://doi.org/10.1023/A:1020466723519