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Hydrocarbonylation of prop-2-en-1-ol catalysed by zeolite-encapsulated rhodium species: chemoselectivity effects imposed by the zeolite support

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Abstract

Zeolite-encapsulated catalysts, [Rh(CO)x(PR3)y]-zeolite, exhibit markedly different chemoselectivities to their homogeneous counterparts; furans and pyrans are formed from the hydrocarbonylation of prop-2-en-1-ol or but-3-en-1-ol instead of the expected diols. The nature of the zeolite support was found to influence the selectivity of the reaction.

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Authors
  1. A.W.S. Currie
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  2. J.M. Andersen
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Currie, A., Andersen, J. Hydrocarbonylation of prop-2-en-1-ol catalysed by zeolite-encapsulated rhodium species: chemoselectivity effects imposed by the zeolite support. Catalysis Letters 44, 109–111 (1997). https://doi.org/10.1023/A:1018960621837

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  • DOI: https://doi.org/10.1023/A:1018960621837

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