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Synthesis and Structure of Tri(p-tolyl)antimony Dichloride

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Abstract

Tri(p-tolyl)antimony dichloride was prepared by oxidation of tri(p-tolyl)stibine with chlorine or copper(II) chloride. As found by X-ray diffraction analysis, the antimony atom in tri(p-tolyl)antimony dichloride has the configuration of trigonal bipyramid with axially located chlorine atoms. The Sb-Cl and Sb-C distances are 2.476(2) and 2.104(7) Å, and the CSbC and ClSbCl angles are 120 and 180°, respectively.

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Authors and Affiliations

  1. Blagoveshchensk State Pedagogical University, Blagoveshchensk, Russia

    V. V. Sharutin, O. K. Sharutina, A. P. Pakusina, T. P. Platonova & V. K. Bel'skii

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  1. V. V. Sharutin
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  2. O. K. Sharutina
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  3. A. P. Pakusina
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  4. T. P. Platonova
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  5. V. K. Bel'skii
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Sharutin, V.V., Sharutina, O.K., Pakusina, A.P. et al. Synthesis and Structure of Tri(p-tolyl)antimony Dichloride. Russian Journal of General Chemistry 72, 392–393 (2002). https://doi.org/10.1023/A:1015491517061

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