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Synergistic Effect in the Catalysis by Pyridine N-Oxide-Triethylamine Mixture of Acyl Transfer Processes with Participation of Benzoyl, Diethoxyphosphinoyl, and p-Toluenesulfonyl Chlorides

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Abstract

The kinetics of benzoylation of substituted phenols with benzoyl chloride in the presence of pyridine N-oxide-triethylamine was analyzed with regard to previously reported data on benzoylation, phosphorylation, and sulfonylation of phenols and carboxylic acids. A common mechanism of the synergistic effect was established. The synergistic effect decreases in the series PhCOCl >> (EtO)2POCl > TsCl.

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Authors and Affiliations

  1. Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences of Ukraine, ul. R. Luxemburg 70, Donetsk, 83114, Ukraine

    I. A. Belousova, V. A. Savelova, Yu. S. Simanenko & B. V. Panchenko

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  1. I. A. Belousova
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  2. V. A. Savelova
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  3. Yu. S. Simanenko
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  4. B. V. Panchenko
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Belousova, I.A., Savelova, V.A., Simanenko, Y.S. et al. Synergistic Effect in the Catalysis by Pyridine N-Oxide-Triethylamine Mixture of Acyl Transfer Processes with Participation of Benzoyl, Diethoxyphosphinoyl, and p-Toluenesulfonyl Chlorides. Russian Journal of Organic Chemistry 38, 111–114 (2002). https://doi.org/10.1023/A:1015319228542

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  • DOI: https://doi.org/10.1023/A:1015319228542

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