Abstract
As a result of modular analysis, relationships between the crystal structures of sulfides and sulfo salts □O[Tm, T′n ]S1-x (x = 0, 1/4) formed by close packing of sulfur atoms have been established. Four basic types of structure corresponding to the construction module of Laves polyhedra (framework, layer, chain, discrete polyhedron) have been revealed. Formation of superspacings ka, where a is the parameter of the commensurate crystal lattices of sphalerite and sulvanite, is analyzed.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
D. J. Vaughan and J. R. Craig, Mineral Chemistry of Metal Sulfides, Cambridge University Press, New York (1978).
F. J. Trojer, Am. Miner., 51, 890-894 (1966).
J. F. Rowland and S. R. Hall, Acta Crystallogr., 21, 2105-2114 (1975).
S. R. Hall and J. F. Rowland, ibid., 29, 2365-2372 (1973).
Y. Kudoh and Y. Takeuchi, Z. Kristallogr., 144, 145-160 (1976).
S. R. Hall and E. J. Gabe, Am. Miner., 57, 368-380 (1972).
P. J. Spry, S. Merlino, S. Wang, et al., ibid., 79, 750-762 (1994).
O. V. Frank-Kamenetskaya, I. V. Rozhdestvenskaya, and L. A. Yanulova, Zh. Strukt. Khim., 43, No. 1 (2002).
R. T. Tettenhorst and C. E. Corbato, Am. Miner., 69, 943-947 (1984).
L. R. Bernstein, D. G. Reichel, and S. Merlino, ibid., 74, 1177-1181 (1989).
B. J. Wuensch, Z. Kristallogr., 119, 437-453 (1964).
N. V. Belov and E. A. Pobedimskaya, Kristallografiya, 13, No. 6, 969-975 (1968).
B. J. Wuensch, Y. Takeuchi, and W. Nowacki, Z. Kristallogr., 123, 1-20 (1966).
I. V. Rozhdestvenskaya, N. V. Zayakina, V. P. Samusikov, Miner. Zh., 15, No. 2, 9-15 (1993).
L. N. Kaplunnik, E. A. Pobedimskaya, and N. V. Belov, Dokl. Akad. Nauk SSSR, 253, No. 1, 105-107 (1980).
E. A. Pobedimskaya, L. N. Kaplunnik, and N. V. Belov, Problems in Crystal Science [in Russian], Vol. 3, Nauka, Moscow (1982), pp. 5-54.
L. N. Kaplunnik, E. A. Pobedimskaya, and N. V. Belov, Dokl. Akad. Nauk SSSR, 225, No. 3, 561-563 (1975).
A. Guinier, G. B. Bokij, K. Boll-Dornberger, et al., Acta Crystallogr., A40, 399-404 (1984).
B. J. Wuensch, Sulfide Mineralogy Short Course Notes, Vol. 1, Washington (1974).
L. Pauling and R. Hultgren, Z. Kristallogr., 84, 204-212 (1933).
L. Pauling, Tschermaks Mineralogisch-Petrographische Mitteilungen, No. 10, 379-384 (1965).
N. V. Belov, Itogi Nauki Tekh., Kristallokhim., 30, 1-265 (1995).
N. V. Belov, Essays in Structural Mineralogy [in Russian], Nedra, Moscow (1976).
I. A. Budko and I. A. Kulagov, Dokl. Akad. Nauk SSSR, 152, 408-410 (1963).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Frank-Kamenetskaya, O.V. Modular Analysis of the Crystal Structures of Sulfides and Sulfo Salts with Occupied Tetrahedra of Two Orientations. Journal of Structural Chemistry 42, 956–966 (2001). https://doi.org/10.1023/A:1015056718761
Issue Date:
DOI: https://doi.org/10.1023/A:1015056718761