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Reactivity of the Lithium Salt of 4H-Cyclopenta[2,1-b:3,4-b']dithiophene

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Abstract

The regioselectivity in reactions of the lithium salt of 4H-cyclopenta[2,1-b:3,4-b']dithiophene with various electrophilic agents [SiMe3Cl, SnMe3Cl, D2O, Re(CO)5Br] is discussed in terms of the charge and orbital control concepts.

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REFERENCES

  1. Voltz, H. and Kowarsch, H., J. Organomet. Chem., 1977, vol. 136, no. 2, p. 27.

  2. Sannicolo, F., Terragni, A., Brenna, E., and Di Silvestro, G., Abstracts of Papers, XI FECHEM Conf. on Organometallic Chemistry, Parma, 1995, p. 27.

  3. Voltz, H. and Kowarsch, H., Tetrahedron Lett., 1976, no. 48, pp. 4376-4378.

    Google Scholar 

  4. Janssen, M.J. and Jong, J. de, Recl. Trav. Chim. Pays-Bas, 1967, vol. 86, no. 11, pp. 1246-1249.

    Google Scholar 

  5. Ewen, J.A., Jones, R.J., Elder, M.J., Rheingold, A.L., and Liable-Sands, L.M., J. Am. Chem. Soc., 1998, vol. 120, no. 41, pp. 10 786-10 790; Ewen, J.A., Jones, R.J., Elder, M.J., and Dubitsky, Yu.A., Int. Patent Appl. WO98/22 486, 1998.

    Google Scholar 

  6. Kissounko, D.A., Oprunenko, Yu.F., Lemenovskii, D.A., and Boag, N.M., Abstracts of Papers, XIII FECHEM Organometallic Conf., Lisbon, 1999, p. 145.

  7. Kissounko, D.A., Oprunenko, Yu.F., Zabalov, M.V., Lemenovskii, D.A., and Boag, N.M., Abstracts of Papers, XIII Int. Organometallic Conf., Shanghai, 2000, p. 91.

  8. Kraak, A., Wiersema, A.K., Jordens, P., and Wynberg, H., Tetrahedron, 1968, vol. 24, no. 12, pp. 3381-3396.

    Google Scholar 

  9. Frisch, M.J., Trucks, G.W., Head-Gordon, M., Gill, P.M.W., Foresman, J.B., Schlegel, H.B., Raghavachari, K., Roff, M.A., Binkley, J.S., Gonzalez, C., Martin, R., Fox, D.J., DeFrees, D.J., Baker, J., Stewart, J.J.P., and Pople, J.A., GAIUSSIAN 94, Rev. C.2, Pittsburgh: Gaussian, 1995.

    Google Scholar 

  10. Biegler-Konig, F.W., Bader, R.F.W., and Tang, T.-H., J. Comput. Chem., 1982, vol. 3, no. 2, p. 317.

    Google Scholar 

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Kisun'ko, D.A., Zabalov, M.V., Myshakin, E.M. et al. Reactivity of the Lithium Salt of 4H-Cyclopenta[2,1-b:3,4-b']dithiophene. Russian Journal of General Chemistry 71, 1751–1753 (2001). https://doi.org/10.1023/A:1013994425157

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