Abstract
An oscillating reaction of alkyne oxidative carbonylation is studied in a PdI2–KI–CH3OH catalytic system. Concentration limits for oscillations are found. A tentative kinetic model for the process is proposed. The mechanism of oscillations is discussed.
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Gorodskii, S.N., Zakharov, A.N., Kulik, A.V. et al. Oxidative Carbonylation of Alkynes in an Oscillation Mode: I. Concentration Limits for Oscillations in the Course of Phenylacetylene Carbonylation and Possible Mechanisms of the Process. Kinetics and Catalysis 42, 251–263 (2001). https://doi.org/10.1023/A:1010477720669
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DOI: https://doi.org/10.1023/A:1010477720669